{rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)(CO)Cl}*0.54CH₂Cl₂

Base Information

• Chemical Name: {rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)(CO)Cl}*0.54CH₂Cl₂
• CAS No.: 113706-05-1
• Molecular Formula: 0CH₂Cl₂*C₂₀H₁₈ClNOPRh
• Molecular Weight: 503.565
• Mol file: 113706-05-1.mol

Synonyms:{rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)(CO)Cl}*0.54CH₂Cl₂

Chemical Property of {rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)(CO)Cl}*0.54CH₂Cl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)(CO)Cl}*0.54CH₂Cl₂

There total 2 articles about {rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)(CO)Cl}*0.54CH₂Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

rhodium(III) chloride trihydrate + 2-(2-(diphenylphosphino)ethyl)pyridine (10150-27-3) → {rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)(CO)Cl}*0.54CH2Cl2 (113706-05-1)

Guidance literature:

With LiCl; CO; In 2-methoxy-ethanol; toluene; byproducts: CO; High Pressure; Under N2, a suspn. of RhCl3*3H2O and LiCl in 2-methoxyethanol is placed under 50 psi CO at 140-145°C for 60-90 min yielding yellow {Rh(CO)2Cl2}(1-). This soln. is filtered, slow addn. of a soln. of PN in toluene gives vigorous CO evolution.; Addn. of Et2O yields a ppt., recrystn. from CH2Cl2/Et2O, elem. anal.;

Reference yield:

di(rhodium)tetracarbonyl dichloride + trans-{iridium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)2(CO)Cl} (113705-93-4) → {rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)(CO)Cl}*0.54CH2Cl2 (113706-05-1) + {iridium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)(CO)Cl} (113705-94-5)

Guidance literature:

Reference yield:

{rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)(CO)Cl}*0.54CH2Cl2 (113706-05-1) + 2-(2-(diphenylphosphino)ethyl)pyridine (10150-27-3) → {rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)2(CO)Cl} (71803-68-4)

Guidance literature:

upstream raw materials:

2-(2-(diphenylphosphino)ethyl)pyridine

trans-{iridium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)2(CO)Cl}

Downstream raw materials:

{rhodium(1-(2-pyridyl)-2-(diphenylphosphino)ethane)2(CO)Cl}