Potassium O-Isobutyl Dithiocarbonate

Base Information

• Chemical Name: Potassium O-Isobutyl Dithiocarbonate
• CAS No.: 13001-46-2
• Molecular Formula: C5H10OS2^.K
• Molecular Weight: 188.356
• Hs Code.: 2930902000
• Mol file: 13001-46-2.mol

Synonyms:Carbonicacid, dithio-, O-isobutyl ester, potassium salt (8CI);Carbonodithioic acid, O-(2-methylpropyl)ester, potassium salt (9CI);Xanthic acid, isobutyl-, potassium salt (7CI);Isobutyl potassium xanthate;O-Isobutyl potassium xanthate;Potassium O-isobutyl xanthate;Potassium isobutoxyxanthogenate;Potassium isobutyl dithiocarbonate;Potassium isobutyl xanthate;Potassium isobutylxanthogenate;

Chemical Property of Potassium O-Isobutyl Dithiocarbonate

Chemical Property:

• Vapor Pressure: 2.91mmHg at 25°C
• Refractive Index: 1.527
• Boiling Point: 161.8 °C at 760 mmHg
• Flash Point: 51.7 °C
• PSA: 66.62000
• Density: 1.098g/cm³
• LogP: 2.14140
• Water Solubility.: 1.512g/L at 25℃

Purity/Quality:

99% ^*data from raw suppliers

POTASSIUM O-ISOBUTYL DITHIOCARBONATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Potassium O-Isobutyl Dithiocarbonate

There total 2 articles about Potassium O-Isobutyl Dithiocarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

carbon disulfide (75-15-0,12122-00-8) + 2-methyl-propan-1-ol (78-83-1) → potassium O-isobutyl dithiocarbonate (13001-46-2)

Guidance literature:

With potassium hydroxide; at 23 ℃; for 4h;

DOI:10.1016/j.poly.2015.11.041

Reference yield:

→ potassium O-isobutyl dithiocarbonate (13001-46-2)

Guidance literature:

Reference yield: 97.0%

2,3,4,6-Tetra-O-benzyl-D-glucopyranose (4291-69-4,6386-24-9,6564-72-3,59531-24-7,69257-52-9,78184-89-1,78609-16-2,78609-17-3,78609-18-4,96553-53-6,104111-61-7,131347-08-5,4132-28-9) + potassium O-isobutyl dithiocarbonate (13001-46-2) → O-isobutyl S-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl) dithiocarbonate (116429-56-2)

Guidance literature:

With sodium hydroxide; p-toluenesulfonyl chloride; tetrabutyl-ammonium chloride; In benzene; for 2h; Ambient temperature;

DOI:10.1016/S0008-6215(00)90908-X

upstream raw materials:

carbon disulfide

2-methyl-propan-1-ol

Downstream raw materials:

O-isobutyl S-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl) dithiocarbonate

O-isobutyl S-(2,3,4,6-tetra-O-benzyl-β-D-mannopyranosyl) dithiocarbonate

O-isobutyl S-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl) dithiocarbonate

O-isobutyl S-(2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl) dithiocarbonate

Refernces

• 1、 Alderhami, Suliman A.,Collison, David,Lewis, David J.,McNaughter, Paul D.,O'Brien, Paul,Spencer, Ben F.,Vitorica-Yrezabal, Inigo,Whitehead, George. "Accessing γ-Ga2S3 by solventless thermolysis of gallium xanthates: A low-temperature limit for crystalline products". . p. 15605 - 15612. Retrieved 2019.
• 2、 Rani, Alka,Gupta. "Synthesis and characterization of various xanthates and their effects on germination and early seedling growth in wheat (Triticum aestivum L.)". . p. 6995 - 6996. Retrieved 2013.
• 3、 -. "Water-soluble triazine xanthogen derivative and its preparation method and application". Paragraph 0029. . Retrieved 2019/03/29.