N,N'-dibenzyl-1,6,7,12-tetraphenoxyperylene-3,4:9,10-tetracarboxylic acid bisimide

Base Information

• Chemical Name: N,N'-dibenzyl-1,6,7,12-tetraphenoxyperylene-3,4:9,10-tetracarboxylic acid bisimide
• CAS No.: 272445-57-5
• Molecular Formula: C₆₂H₃₈N₂O₈
• Molecular Weight: 938.992
• Mol file: 272445-57-5.mol

Synonyms:N,N'-dibenzyl-1,6,7,12-tetraphenoxyperylene-3,4:9,10-tetracarboxylic acid bisimide

Chemical Property of N,N'-dibenzyl-1,6,7,12-tetraphenoxyperylene-3,4:9,10-tetracarboxylic acid bisimide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-dibenzyl-1,6,7,12-tetraphenoxyperylene-3,4:9,10-tetracarboxylic acid bisimide

There total 1 articles about N,N'-dibenzyl-1,6,7,12-tetraphenoxyperylene-3,4:9,10-tetracarboxylic acid bisimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzylamine (100-46-9) + 1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride (156028-26-1) + phenol (108-95-2,27073-41-2) → N,N'-dibenzyl-1,6,7,12-tetraphenoxyperylene-3,4:9,10-tetracarboxylic acid bisimide (272445-57-5)

Guidance literature:

benzylamine; 1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride; With propionic acid; at 140 ℃; for 8h;

phenol; With 1-methyl-pyrrolidin-2-one; potassium carbonate; at 130 ℃; for 16h; Further stages.;

DOI:10.1021/jo011133l

Reference yield: 68.0%

N,N'-dibenzyl-1,6,7,12-tetraphenoxyperylene-3,4:9,10-tetracarboxylic acid bisimide (272445-57-5) → 5,6,12,13-tetraphenoxy-1,3,8,10-tetrahydro-2,9-dibenzyl-2,9-diazadibenzo[cd,lm]perylene

Guidance literature:

With lithium aluminium tetrahydride; aluminium trichloride; In tetrahydrofuran; at 35 ℃; for 6h;

DOI:10.1002/(SICI)1521-3773(20000403)39:7<1243::AID-ANIE1243>3.0.CO;2-Z

Reference yield:

N,N'-dibenzyl-1,6,7,12-tetraphenoxyperylene-3,4:9,10-tetracarboxylic acid bisimide (272445-57-5) → 5,6,12,13-Tetraphenoxy-2,9-diazadibenzo[cd,lm]perylene (272445-61-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 68 percent / lithium aluminum hydride; aluminum chloride / tetrahydrofuran / 6 h / 35 °C

2: 48 percent / 10percent Pd/C / diphenyl ether / 6 h / 170 °C

With lithium aluminium tetrahydride; aluminium trichloride; 10percent Pd/C; In tetrahydrofuran; diphenylether;

DOI:10.1021/jo011133l

upstream raw materials:

benzylamine

1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride

phenol

Downstream raw materials:

5,6,12,13-Tetraphenoxy-2,9-diazadibenzo[cd,lm]perylene