tert-butyl 3-<4-<(tert-butyldimethylsilyl)oxy>phenyl>-3-<<(methoxyethoxy)methyl>oxy>propanoate

Base Information

Chemical Name:tert-butyl 3-<4-<(tert-butyldimethylsilyl)oxy>phenyl>-3-<<(methoxyethoxy)methyl>oxy>propanoate
CAS No.:132777-18-5
Molecular Formula:C₂₃H₄₀O₆Si
Molecular Weight:440.653
Hs Code.:

Synonyms:tert-butyl 3-<4-<(tert-butyldimethylsilyl)oxy>phenyl>-3-<<(methoxyethoxy)methyl>oxy>propanoate

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Chemical Property of tert-butyl 3-<4-<(tert-butyldimethylsilyl)oxy>phenyl>-3-<<(methoxyethoxy)methyl>oxy>propanoate

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Technology Process of tert-butyl 3-<4-<(tert-butyldimethylsilyl)oxy>phenyl>-3-<<(methoxyethoxy)methyl>oxy>propanoate

There total 5 articles about tert-butyl 3-<4-<(tert-butyldimethylsilyl)oxy>phenyl>-3-<<(methoxyethoxy)methyl>oxy>propanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 3970-21-6
2-Methoxyethoxymethyl chloride

: 132777-16-3
tert-butyl 3-<4-<(tert-butyldimethylsilyl)oxy>phenyl>-3-hydroxypropanoate

: 132777-18-5
tert-butyl 3-<4-<(tert-butyldimethylsilyl)oxy>phenyl>-3-<<(methoxyethoxy)methyl>oxy>propanoate

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 23 ℃; for 3.5h;
DOI:10.1021/jo00008a049

Reference yield:

: 540-88-5
acetic acid tert-butyl ester

: 132777-18-5
tert-butyl 3-<4-<(tert-butyldimethylsilyl)oxy>phenyl>-3-<<(methoxyethoxy)methyl>oxy>propanoate

Guidance literature:: Multi-step reaction with 2 steps

1: 1) n-BuLi / 1) THF, -76 deg C, 10 min, 2) THF, 1 h

2: 90 percent / diisopropylethyl amine / CH₂Cl₂ / 3.5 h / 23 °C

With n-butyllithium; N-ethyl-N,N-diisopropylamine; In dichloromethane;
DOI:10.1021/jo00008a049

Reference yield:

: 120743-99-9
p-[(tert-butyldimethylsilyl)oxy]benzaldehyde

: 132777-18-5
tert-butyl 3-<4-<(tert-butyldimethylsilyl)oxy>phenyl>-3-<<(methoxyethoxy)methyl>oxy>propanoate

Guidance literature:: Multi-step reaction with 2 steps

1: 1) n-BuLi / 1) THF, -76 deg C, 10 min, 2) THF, 1 h

2: 90 percent / diisopropylethyl amine / CH₂Cl₂ / 3.5 h / 23 °C

With n-butyllithium; N-ethyl-N,N-diisopropylamine; In dichloromethane;
DOI:10.1021/jo00008a049