C₃₅H₂₉NO₉

Base Information

• Chemical Name: C₃₅H₂₉NO₉
• CAS No.: 1315503-86-6
• Molecular Formula: C₃₅H₂₉NO₉
• Molecular Weight: 607.617
• Mol file: 1315503-86-6.mol

Synonyms:C₃₅H₂₉NO₉

Chemical Property of C₃₅H₂₉NO₉

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₅H₂₉NO₉

There total 16 articles about C₃₅H₂₉NO₉ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

C35H31NO9 (1315504-12-1) → C35H29NO9 (1315504-13-2) + C35H29NO9 (1315503-86-6)

Guidance literature:

With sodium ethanolate; In ethanol; at 20 - 60 ℃; for 18h; Molecular sieve;

DOI:10.1021/ja205339p

Reference yield:

7-(benzyloxy)-4-(methoxymethoxy)-3-oxo-1,3-dihydroisobenzofuran-1-carbonitrile (1315503-82-2) → C35H29NO9 (1315504-13-2) + C35H29NO9 (1315503-86-6)

Guidance literature:

Multi-step reaction with 6 steps

1.1: lithium hexamethyldisilazane / tetrahydrofuran / 0.67 h / -78 °C

1.2: 0.08 h / 0 °C

2.1: borane-THF; (S)-Corey-Bakshi-Shibata oxazaborolidine / tetrahydrofuran; toluene / 2.5 h / -20 °C

3.1: ammonium cerium (IV) nitrate / water; acetonitrile / 0 °C

4.1: silver(l) oxide / dichloromethane / 18 h / 20 °C / Molecular sieve

5.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.17 h / 0 °C

6.1: sodium ethanolate / ethanol / 18 h / 20 - 60 °C / Molecular sieve

With ammonium cerium (IV) nitrate; borane-THF; tetrabutyl ammonium fluoride; sodium ethanolate; silver(l) oxide; lithium hexamethyldisilazane; (S)-Corey-Bakshi-Shibata oxazaborolidine; In tetrahydrofuran; ethanol; dichloromethane; water; toluene; acetonitrile;

DOI:10.1021/ja205339p

Reference yield:

C34H40O7Si (1315503-84-4) → C35H29NO9 (1315504-13-2) + C35H29NO9 (1315503-86-6)

Guidance literature:

Multi-step reaction with 5 steps

1: borane-THF; (S)-Corey-Bakshi-Shibata oxazaborolidine / tetrahydrofuran; toluene / 2.5 h / -20 °C

2: ammonium cerium (IV) nitrate / water; acetonitrile / 0 °C

3: silver(l) oxide / dichloromethane / 18 h / 20 °C / Molecular sieve

4: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.17 h / 0 °C

5: sodium ethanolate / ethanol / 18 h / 20 - 60 °C / Molecular sieve

With ammonium cerium (IV) nitrate; borane-THF; tetrabutyl ammonium fluoride; sodium ethanolate; silver(l) oxide; (S)-Corey-Bakshi-Shibata oxazaborolidine; In tetrahydrofuran; ethanol; dichloromethane; water; toluene; acetonitrile;

DOI:10.1021/ja205339p

upstream raw materials:

7-(benzyloxy)-4-hydroxy-3-oxo-1,3-dihydroisobenzofuran-1-carbonitrile

7-(benzyloxy)-4-(methoxymethoxy)-3-oxo-1,3-dihydroisobenzofuran-1-carbonitrile

C₃₄H₄₀O₇Si

C₃₄H₄₀O₇Si

Downstream raw materials:

C₄₀H₃₁NO₈

C₄₂H₃₅NO₉