Borate(1-),tetrahydro-, zirconium(4+) (4:1) (9CI)

Base Information

• Chemical Name: Borate(1-),tetrahydro-, zirconium(4+) (4:1) (9CI)
• CAS No.: 23840-95-1
• Molecular Formula: B₄H₁₆Zr
• Molecular Weight: 150.595
• Mol file: 23840-95-1.mol

Synonyms:Borate(1-),tetrahydro-, zirconium(4+) (8CI); Zirconium tetraborohydride; Zirconium(4+)tetrahydroborate

Chemical Property of Borate(1-),tetrahydro-, zirconium(4+) (4:1) (9CI)

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): 3
• Hazard Codes: 3:
• Safety Statements: Violent reaction with air. See also BORON COMPOUNDS and ZIRCONIUM COMP"> BORON COMPOUNDS and ZIRCONIUM COMPOUNDS." target="_blank">Violent reaction with air. See also BORON COMPOUNDS and ZIRCONIUM COMP

MSDS Files:

Useful:

Technology Process of Borate(1-),tetrahydro-, zirconium(4+) (4:1) (9CI)

There total 2 articles about Borate(1-),tetrahydro-, zirconium(4+) (4:1) (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

lithium borohydride + zirconium(IV) chloride (10026-11-6) → zirconium(IV) tetrakis(tetrahydroborate) (12370-59-1,23840-95-1)

Guidance literature:

In neat (no solvent); according to: Davies, N., Saunders, D; Wallbridge, M. G. H. J. Chem. Soc. A 1970, 2915; mixing under vac., mixt. was stirred for 1 h at room temp., cooled to 77 K, warmed to room temp. under pumping, condensed at 163K; crude solid was purified by revaporization at 273 K and trapping at 195 K; IR;

DOI:10.1021/ic020357z

Reference yield:

lithium borohydride + zirconium(IV) chloride (10026-11-6) → zirconium(IV) borohydride (12370-59-1,23840-95-1)

Guidance literature:

In solid; stirring above 29 °C; vacuum sublimation into a chilled flask;

DOI:10.1111/j.1151-2916.1988.tb05867.x

Reference yield:

zirconium(IV) borohydride (12370-59-1,23840-95-1) → zirconium diboride (12045-64-6)

Guidance literature:

In gas; Irradiation (UV/VIS); laser chemical vapor deposition in an irradiation cell (pressure: 240 Pa to 2 kPa), CO2 IR-laser (10.6 μm, cw: 20 W, pulsed: 2 J/pulse) or Nd-YAG laser (1.06 μm, 200 mJ/pulse);

DOI:10.1111/j.1151-2916.1988.tb05867.x

upstream raw materials:

zirconium(IV) chloride

Downstream raw materials:

zirconium diboride

Refernces

• 1、 Rice,Woodin. "ZIRCONIUM BOROHYDRIDE AS A ZIRCONIUM BORIDE PRECURSOR.". . p. c181-c183. Retrieved 2008/10/08.