endo-(1S,2R,3R,4R)-3-(4-methoxyphenyl)bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde

Base Information

Chemical Name:endo-(1S,2R,3R,4R)-3-(4-methoxyphenyl)bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde
CAS No.:1032817-88-1
Molecular Formula:C₁₅H₁₆O₂
Molecular Weight:228.291
Hs Code.:

Synonyms:endo-(1S,2R,3R,4R)-3-(4-methoxyphenyl)bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of endo-(1S,2R,3R,4R)-3-(4-methoxyphenyl)bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde

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Technology Process of endo-(1S,2R,3R,4R)-3-(4-methoxyphenyl)bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde

There total 5 articles about endo-(1S,2R,3R,4R)-3-(4-methoxyphenyl)bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 24680-50-0,71277-11-7,1963-36-6
4-methoxy-trans-cinnamaldehyde

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 1069084-47-4
(1S,2S,3S,4R)-3‐(4-methoxyphenyl)bicyclo[2.2.1]hept‐5‐ene‐2‐carbaldehyde

: 1032817-87-0
3‐(4-methoxyphenyl)bicyclo[2.2.1]hept‐5‐ene‐2‐carbaldehyde

: 1032817-88-1
endo-(1S,2R,3R,4R)-3-(4-methoxyphenyl)bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde

: 1301133-89-0
endo-(1R,2S,3S,4S)-3-(4-methoxyphenyl)bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde

Guidance literature:: With perchloric acid; (2S,2'S,3R,3'R)-3,3'-bis(benzyloxy)-2,2'-bipyrrolidine; In water; at 20 ℃; for 3.5h; optical yield given as %ee; enantioselective reaction;
DOI:10.1016/j.tet.2010.03.042

Reference yield:

: 24680-50-0,71277-11-7,1963-36-6
4-methoxy-trans-cinnamaldehyde

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 1069084-47-4
(1S,2S,3S,4R)-3‐(4-methoxyphenyl)bicyclo[2.2.1]hept‐5‐ene‐2‐carbaldehyde

: 1032817-87-0
3‐(4-methoxyphenyl)bicyclo[2.2.1]hept‐5‐ene‐2‐carbaldehyde

: 1032817-88-1
endo-(1S,2R,3R,4R)-3-(4-methoxyphenyl)bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde

Guidance literature:: With C₁₂H₂₂N₂O₂S; trichloroacetic acid; In sodium chloride; at 20 ℃; for 24h; optical yield given as %ee; enantioselective reaction;
DOI:10.1021/ol8005826

Reference yield:

: 1963-36-6
4-methoxycinnamaldehyde

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 1069084-47-4
(1S,2S,3S,4R)-3‐(4-methoxyphenyl)bicyclo[2.2.1]hept‐5‐ene‐2‐carbaldehyde

: 1032817-88-1
endo-(1S,2R,3R,4R)-3-(4-methoxyphenyl)bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde

: 1301133-89-0
endo-(1R,2S,3S,4S)-3-(4-methoxyphenyl)bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde

Guidance literature:: With (S)-2-[bis(3,5-bis(trifluoromethyl)phenyl)-triethyl-siloxy-methyl]-pyrrolidine; trifluoroacetic acid; In toluene; at 20 ℃; for 72h; enantioselective reaction;
DOI:10.1002/adsc.201900061