(1S,2S,3S,4R)-3‐(4-methoxyphenyl)bicyclo[2.2.1]hept‐5‐ene‐2‐carbaldehyde

Base Information

Chemical Name:(1S,2S,3S,4R)-3‐(4-methoxyphenyl)bicyclo[2.2.1]hept‐5‐ene‐2‐carbaldehyde
CAS No.:1069084-47-4
Molecular Formula:C₁₅H₁₆O₂
Molecular Weight:228.291
Hs Code.:

Synonyms:(1S,2S,3S,4R)-3‐(4-methoxyphenyl)bicyclo[2.2.1]hept‐5‐ene‐2‐carbaldehyde

Suppliers and Price of (1S,2S,3S,4R)-3‐(4-methoxyphenyl)bicyclo[2.2.1]hept‐5‐ene‐2‐carbaldehyde

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,2S,3S,4R)-3‐(4-methoxyphenyl)bicyclo[2.2.1]hept‐5‐ene‐2‐carbaldehyde

Chemical Property:

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Technology Process of (1S,2S,3S,4R)-3‐(4-methoxyphenyl)bicyclo[2.2.1]hept‐5‐ene‐2‐carbaldehyde

There total 13 articles about (1S,2S,3S,4R)-3‐(4-methoxyphenyl)bicyclo[2.2.1]hept‐5‐ene‐2‐carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 24680-50-0,71277-11-7,1963-36-6
4-methoxy-trans-cinnamaldehyde

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 1069084-47-4
(1S,2S,3S,4R)-3‐(4-methoxyphenyl)bicyclo[2.2.1]hept‐5‐ene‐2‐carbaldehyde

: 1032817-87-0
3‐(4-methoxyphenyl)bicyclo[2.2.1]hept‐5‐ene‐2‐carbaldehyde

: 1032817-88-1
endo-(1S,2R,3R,4R)-3-(4-methoxyphenyl)bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde

: 1301133-89-0
endo-(1R,2S,3S,4S)-3-(4-methoxyphenyl)bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde

Guidance literature:: With perchloric acid; (2S,2'S,3R,3'R)-3,3'-bis(benzyloxy)-2,2'-bipyrrolidine; In water; at 20 ℃; for 3.5h; optical yield given as %ee; enantioselective reaction;
DOI:10.1016/j.tet.2010.03.042

Reference yield:

: 1963-36-6
4-methoxycinnamaldehyde

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 1069084-47-4
(1S,2S,3S,4R)-3‐(4-methoxyphenyl)bicyclo[2.2.1]hept‐5‐ene‐2‐carbaldehyde

: 1032817-87-0
3‐(4-methoxyphenyl)bicyclo[2.2.1]hept‐5‐ene‐2‐carbaldehyde

: 1301133-89-0
endo-(1R,2S,3S,4S)-3-(4-methoxyphenyl)bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde

Guidance literature:: With 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide immobilized MacMillan imidazolidine catalyst in silica bed; In tert-Amyl alcohol; at 20 ℃; for 46h; optical yield given as %ee; enantioselective reaction;
DOI:10.1002/adsc.200900865

Reference yield:

: 1963-36-6
4-methoxycinnamaldehyde

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 1069084-47-4
(1S,2S,3S,4R)-3‐(4-methoxyphenyl)bicyclo[2.2.1]hept‐5‐ene‐2‐carbaldehyde

: C₁₅H₁₈O

Guidance literature:: With perchloric acid; C₅₇H₇₆N₈O₈; In water; acetonitrile; at 25 ℃; for 24h; Overall yield = 82 %; enantioselective reaction;
DOI:10.1007/s10562-016-1724-7