methyl 1-benzyloxycarbonyl-(4S)-phenylseleno-(2S)-pyrrolidinylcarboxylate

Base Information

Chemical Name:methyl 1-benzyloxycarbonyl-(4S)-phenylseleno-(2S)-pyrrolidinylcarboxylate
CAS No.:84062-30-6
Molecular Formula:C₂₀H₂₁NO₄Se
Molecular Weight:418.351
Hs Code.:

Synonyms:methyl 1-benzyloxycarbonyl-(4S)-phenylseleno-(2S)-pyrrolidinylcarboxylate

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Chemical Property of methyl 1-benzyloxycarbonyl-(4S)-phenylseleno-(2S)-pyrrolidinylcarboxylate

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of methyl 1-benzyloxycarbonyl-(4S)-phenylseleno-(2S)-pyrrolidinylcarboxylate

There total 5 articles about methyl 1-benzyloxycarbonyl-(4S)-phenylseleno-(2S)-pyrrolidinylcarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 1666-13-3
diphenyl diselenide

: 57653-38-0
N-<(phenylmethoxy)carbonyl>-4(R)-<<(4-methylphenyl)sulfonyl>oxy>-(S)-proline methyl ester

: 84062-30-6
methyl 1-benzyloxycarbonyl-(4S)-phenylseleno-(2S)-pyrrolidinylcarboxylate

Guidance literature:: With sodium tetrahydroborate; In methanol; for 5h; Heating;
DOI:10.1016/j.bmc.2005.11.058

Reference yield:

: 64187-48-0
methyl (2S,4R)-1-benzyloxycarbonyl-4-hydroxypyrrolidine-2-carboxylate

: 84062-30-6
methyl 1-benzyloxycarbonyl-(4S)-phenylseleno-(2S)-pyrrolidinylcarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / methyl triflate; N-methylimidazole / tetrahydrofuran / 0 - 20 °C

2: 82 percent / NaBH₄ / methanol / 5 h / Heating

With 1-methyl-1H-imidazole; sodium tetrahydroborate; methyl trifluoromethanesulfonate; In tetrahydrofuran; methanol;
DOI:10.1016/j.bmc.2005.11.058

Reference yield:

: 13504-85-3
(2S,4R)-1-(benzyloxycarbonyl)-4-hydroxypyrrolidine-2-carboxylic acid

: 84062-30-6
methyl 1-benzyloxycarbonyl-(4S)-phenylseleno-(2S)-pyrrolidinylcarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: HCl / dioxane / 3 h / Heating

2: pyridine / 168 h / 5 °C

3: NaBH₄ / methanol / 18 h / Heating

With pyridine; hydrogenchloride; sodium tetrahydroborate; In 1,4-dioxane; methanol;
DOI:10.1016/0008-6215(94)84059-8