N-H-N'-phenyl-S-phenyl-S-methyl sulfondiimine

Base Information

• Chemical Name: N-H-N'-phenyl-S-phenyl-S-methyl sulfondiimine
• CAS No.: 1378302-79-4
• Molecular Formula: C₁₃H₁₄N₂S
• Molecular Weight: 230.334
• Mol file: 1378302-79-4.mol

Synonyms:N-H-N'-phenyl-S-phenyl-S-methyl sulfondiimine

Chemical Property of N-H-N'-phenyl-S-phenyl-S-methyl sulfondiimine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-H-N'-phenyl-S-phenyl-S-methyl sulfondiimine

There total 7 articles about N-H-N'-phenyl-S-phenyl-S-methyl sulfondiimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

N-(4-methoxyphenyl)-N'-phenyl-S-methyl-S-phenyl sulfondiimine (1438414-24-4) → N-H-N'-phenyl-S-phenyl-S-methyl sulfondiimine (1378302-79-4)

Guidance literature:

N-(4-methoxyphenyl)-N'-phenyl-S-methyl-S-phenyl sulfondiimine; With ammonium cerium (IV) nitrate; sodium carbonate; In water; acetonitrile; for 0.166667h; Cooling with ice;

With ammonium cerium (IV) nitrate; In water; acetonitrile; at 20 ℃; for 1h;

DOI:10.1002/adsc.201200754

Reference yield: 70.0%

aniline (62-53-3) + S-methyl-S-phenyl sulfiliminium mesitylenesulfonate → N-H-N'-phenyl-S-phenyl-S-methyl sulfondiimine (1378302-79-4) + S-methyl-S-phenylsulfoximine (4381-25-3)

Guidance literature:

S-methyl-S-phenyl sulfiliminium mesitylenesulfonate; With N-chloro-succinimide; sodium carbonate; In N,N-dimethyl-formamide; at 0 ℃; for 5h; Inert atmosphere;

aniline; In N,N-dimethyl-formamide; at 20 ℃; for 12h; Inert atmosphere;

DOI:10.1002/anie.201201296

Reference yield: 42.0%

aniline (62-53-3) + S-methyl-S-phenyl sulfiliminium mesitylenesulfonate → racemic methyl phenyl sulfoxide (1193-82-4) + N-H-N'-phenyl-S-phenyl-S-methyl sulfondiimine (1378302-79-4) + S-methyl-S-phenylsulfoximine (4381-25-3)

Guidance literature:

S-methyl-S-phenyl sulfiliminium mesitylenesulfonate; With sodium carbonate; Selectfluor; In N,N-dimethyl-formamide; at 0 ℃; for 5h; Inert atmosphere;

aniline; In N,N-dimethyl-formamide; at 20 ℃; for 12h; Inert atmosphere;

DOI:10.1002/anie.201201296

upstream raw materials:

aniline

methyl-phenyl-thioether

N-(4-methoxyphenyl)-N'-phenyl-S-methyl-S-phenyl sulfondiimine

Downstream raw materials:

(R)-N-H-N'-phenyl-S-methyl-S-phenylsulfodiimide

(S)-N-H-N'-phenyl-S-methyl-S-phenylsulfodiimide

N-phenyl-N'-cyano-S-methyl-S-phenyl sulfondiimine

N-phenyl-N'-(2-nitrophenyl)-S-methyl-S-phenyl sulfondiimine