[Pt(IV)2(triflate)2Me4(κ3:κ3-1,2,4,5-tetrakis(5-(p-C7H15C6H4)-7-azaindol-1-yl)benzene)]

Base Information

• Chemical Name: [Pt(IV)2(triflate)2Me4(κ3:κ3-1,2,4,5-tetrakis(5-(p-C7H15C6H4)-7-azaindol-1-yl)benzene)]
• CAS No.: 1205548-83-9
• Molecular Formula: C₉₂H₁₀₆F₆N₈O₆Pt₂S₂
• Molecular Weight: 1988.19
• Mol file: 1205548-83-9.mol

Synonyms:[Pt(IV)2(triflate)2Me4(κ3:κ3-1,2,4,5-tetrakis(5-(p-C7H15C6H4)-7-azaindol-1-yl)benzene)]

Chemical Property of [Pt(IV)2(triflate)2Me4(κ3:κ3-1,2,4,5-tetrakis(5-(p-C7H15C6H4)-7-azaindol-1-yl)benzene)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pt(IV)2(triflate)2Me4(κ3:κ3-1,2,4,5-tetrakis(5-(p-C7H15C6H4)-7-azaindol-1-yl)benzene)]

There total 1 articles about [Pt(IV)2(triflate)2Me4(κ3:κ3-1,2,4,5-tetrakis(5-(p-C7H15C6H4)-7-azaindol-1-yl)benzene)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

[Pt(II)2Me4(1,2,4,5-tetrakis(5-(p-C7H15C6H4)-7-azaindol-1-yl)benzene)] (1205548-69-1) + methyl trifluoromethanesulfonate (333-27-7) → [Pt(IV)2(triflate)2Me4(κ3:κ3-1,2,4,5-tetrakis(5-(p-C7H15C6H4)-7-azaindol-1-yl)benzene)] (1205548-83-9) + [Pt(IV)2Me6(1,2,4,5-tetrakis(5-(p-C7H15C6H4)-7-azaindol-1-yl)benzene)](triflate)2

Guidance literature:

With O₂; In benzene; byproducts: CH3OOCH3; (Schlenk technique); keeping benzene soln. of platinum compd. at room temp. under O2 for 3 d, addn. of methyl triflate, shaking for few secs, heating to 60°C for 5 min; cooling, evapn., washing with dry diethyl ether, drying in vac., elem. anal.;

DOI:10.1021/om901046p

Reference yield:

[Pt(IV)2(triflate)2Me4(κ3:κ3-1,2,4,5-tetrakis(5-(p-C7H15C6H4)-7-azaindol-1-yl)benzene)] (1205548-83-9) → platinum (7440-06-4)

Guidance literature:

With (CH₃CH₂CH₂CH₂)4NBH₄; In benzene-d6; byproducts: H2, C6H2(C7H4N2(C6H4C7H15))4; (N2, Schlenk technique); treatment of platinum compd. with hydridoboratesalt in C6D6 at room temp. for few ds; NMR monitoring;

DOI:10.1021/om901046p

upstream raw materials:

[Pt(II)2Me₄(1,2,4,5-tetrakis(5-(p-C₇H₁₅C₆H₄)-7-azaindol-1-yl)benzene)]

methyl trifluoromethanesulfonate

Downstream raw materials:

platinum