(Z)-2-Diazonio-1-(2-methylphenyl)ethen-1-olate

Base Information

Chemical Name:(Z)-2-Diazonio-1-(2-methylphenyl)ethen-1-olate
CAS No.:41441-74-1
Molecular Formula:C₉H₈N₂O
Molecular Weight:160.175
Hs Code.:
DSSTox Substance ID:DTXSID20560959
Nikkaji Number:J306.520K
Wikidata:Q82444615

Synonyms:41441-74-1;SCHEMBL9448877;2-diazo-1-(o-tolyl)-ethanone;DTXSID20560959;2'-Methyl-alpha-diazoacetophenone;(Z)-2-Diazonio-1-(2-methylphenyl)ethen-1-olate

Suppliers and Price of (Z)-2-Diazonio-1-(2-methylphenyl)ethen-1-olate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
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Total 0 raw suppliers

Chemical Property of (Z)-2-Diazonio-1-(2-methylphenyl)ethen-1-olate

Chemical Property:

XLogP3:2.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:160.063662883
Heavy Atom Count:12
Complexity:219

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=CC=C1C(=O)C=[N+]=[N-]

Technology Process of (Z)-2-Diazonio-1-(2-methylphenyl)ethen-1-olate

There total 6 articles about (Z)-2-Diazonio-1-(2-methylphenyl)ethen-1-olate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 847500-51-0
1,3-bis(2-methylphenyl)propan-1,3-dione

: 41441-74-1
o-methyl-α-diazoacetophenone

Guidance literature:: With 4-toluenesulfonyl azide; methylamine; In ethanol; water; at 50 ℃; for 2h;
DOI:10.1021/acs.joc.7b01187

Reference yield:

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 933-88-0
ortho-toluoyl chloride

: 41441-74-1
o-methyl-α-diazoacetophenone

Guidance literature:: With triethylamine; In diethyl ether; at 0 ℃; Yield given;
DOI:10.1021/jo00288a052

Reference yield:

: 118-90-1
ortho-methylbenzoic acid

: 41441-74-1
o-methyl-α-diazoacetophenone

Guidance literature:: Multi-step reaction with 2 steps

1: SOCl₂ / 2 h / Ambient temperature

2: diethyl ether / 0.5 h / 0 °C

With thionyl chloride; In diethyl ether;
DOI:10.1016/S0968-0896(97)00083-7