trichloro(4'-(4-tolyl)-2,2':6',2''-terpyridine)iridium(III)

Base Information

• Chemical Name: trichloro(4'-(4-tolyl)-2,2':6',2''-terpyridine)iridium(III)
• CAS No.: 227949-62-4
• Molecular Formula: C₂₂H₁₇Cl₃IrN₃
• Molecular Weight: 621.976
• Mol file: 227949-62-4.mol

Synonyms:trichloro(4'-(4-tolyl)-2,2':6',2''-terpyridine)iridium(III)

Chemical Property of trichloro(4'-(4-tolyl)-2,2':6',2''-terpyridine)iridium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of trichloro(4'-(4-tolyl)-2,2':6',2''-terpyridine)iridium(III)

There total 6 articles about trichloro(4'-(4-tolyl)-2,2':6',2''-terpyridine)iridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.5%

iridium(III) chloride n-hydrate + 4'-(4-methylphenyl)-2,2':6',2-terpyridine (89972-77-0) → trichloro(4'-(4-tolyl)-2,2':6',2''-terpyridine)iridium(III) (227949-62-4)

Guidance literature:

In ethylene glycol; at 180 ℃; for 0.25h;

Reference yield: 45.0%

iridium(III) chloride + 4'-(4-methylphenyl)-2,2':6',2-terpyridine (89972-77-0) → trichloro(4'-(4-tolyl)-2,2':6',2''-terpyridine)iridium(III) (227949-62-4)

Guidance literature:

In ethylene glycol; at 160 ℃; for 1h;

DOI:10.1021/ja4092165

Reference yield: 15.0%

ammonium hexachloroiridate(III) + 4'-(4-methylphenyl)-2,2':6',2-terpyridine (89972-77-0) → trichloro(4'-(4-tolyl)-2,2':6',2''-terpyridine)iridium(III) (227949-62-4)

Guidance literature:

In ethylene glycol; other Radiation; under N2; suspn. of stoich. amts. of Ir complex and terpyridine deriv. in ethylene glycol refluxed in a microwave oven for 15 min; cooled to room temp., ppt. filtered off under vac., dissolved in CH3CN; elem. anal.;

DOI:10.1002/ejic.200801139

upstream raw materials:

4'-(4-methylphenyl)-2,2':6',2-terpyridine

4-methyl-benzaldehyde

2-acetylpyridine

Downstream raw materials:

[Ir(4'-(C₆H₄CH₃-p)-2,2':6',2''-terpyridine)(CF₃SO₃)3]