89972-77-0

Usage

Uses

Used in Coordination Chemistry:
Used in Ruthenium Complexes:
4'-(4-METHYLPHENYL)-2,2':6',2''-TERPYRIDINE is used as a ligand in the synthesis of terpyridine Ru(II) complexes. These complexes have potential applications in various fields, such as catalysis, photovoltaics, and as luminescent or redox-active materials.
Used in Cadmium and Mercury Complexes:
4'-(4-METHYLPHENYL)-2,2':6',2''-TERPYRIDINE is used as a ligand in the synthesis of terpyridine-based Cd(II) and Hg(II) complexes. These complexes can be employed in studies related to coordination chemistry, as well as potential applications in sensing or environmental remediation.
Used in Heterobimetallic Complexes:
4'-(4-METHYLPHENYL)-2,2':6',2''-TERPYRIDINE is used as a ligand in the synthesis of heterobimetallic Ru(II)-Os(II) complexes. These complexes can exhibit unique electronic properties and may have potential applications in areas such as molecular electronics or as catalysts for specific chemical reactions.

Upstream product

• 26482-00-8 1-(2-oxo-2-(2-pyridyl)ethyl)pyridinium iodide 
• 158014-83-6 (E)‐1‐(pyridin‐2‐yl)‐3‐(p‐tolyl)prop‐2‐en‐1‐one 
• 209114-52-3 1,5-di(2-pyridinyl)-3-p-tolylpentane-1,5-dione 
• 1122-62-9 2-acetylpyridine 
• 104-87-0 4-methyl-benzaldehyde 
• 92206-38-7 ammonium acetate 
• 24582-66-9 1-(2-pyridyl)-3-(4-tolyl)propen-1-one 
• 17084-13-8 potassium hexafluorophosphate 

Downstream Products

• 89972-78-1 4'-(4-bromomethylphenyl)-2,2':6',2''-terpyridine 
• 181281-10-7 4'-p-Tolyl-[2,2';6',2'']terpyridine 1,1''-dioxide 
• 138253-30-2 4'-(4-formylphenyl)-[2,2':6',2'']terpyridine 
• 263708-67-4 diethyl 4-([2,2’:6’,2”-terpyridine]-4’-yl)benzylphosphonate 
• 1026009-09-5 4-{(E)-2-[4-((E)-2-{2,5-Dipropoxy-4-[(E)-2-(4-[2,2';6',2'']terpyridin-4'-yl-phenyl)-vinyl]-phenyl}-vinyl)-phenyl]-vinyl}-2,5-dipropoxy-benzaldehyde 
• 227949-62-4 trichloro(4'-(4-tolyl)-2,2':6',2''-terpyridine)iridium(III) 
• 138645-44-0 Os(tterpy)2⁽²⁺⁾ 
• 121810-59-1 [Ru(4'-p-tolyl-2,2':6',2''-terpyridine)2](2+) 
• 136247-52-4 {(4'-p-tolyl-2,2':6',2''-terpyridine)(4'-(p-(1-methyl-4,4'-bipyridinium-1'-yl)methylphenyl)-2,2':6',2''-terpyridine)ruthenium}(PF₆)4 
• 136247-54-6 {(4'-(p-(1-methyl-4,4'-bipyridinium-1'-yl)methylphenyl)-2,2':6',2''-terpyridine)2ruthenium}(PF₆)6 

Relevant academic research and scientific papers

Orange Fluorescent Ru(III) Complexes Based on 4′-Aryl Substituted 2,2′:6′,2″-Terpyridine for OLEDs Application

A series of ruthenium (III) complexes of the formulae [Ru(4-Mephtpy)2]Cl3(1) [Ru(L1)], [Ru(3,4,5-tmphtpy)2]Cl3(2) [Ru(L2)], and [Ru(4-thptpy)2]Cl3(3) [Ru(L3

A long-lived Donor–Acceptor fluorescent probe for sequential detection of Cu2+ and biothiols

A new long-lived Donor–Acceptor (D–A) fluorophore based on carbazolyl dicyanobenzene was developed as an ON–OFF–ON multifunctional fluorescent probe 1 for sequential detection of Cu2+ and biothiols (Cys, Hcy and GSH). The fluorescence of probe

Complexes of a [2]rotaxane ligand with terminal terpyridine groups

Permanently interlocked [2]rotaxane ligands can be created by capping a pyridine terminated [2]pseudorotaxane with terpyridine containing stoppers. The robust nature of the resulting [2]rotaxane ligand allows coordination to inert metals such as Ru(ii) no

A multi-color and white-light emissive cucurbituril/terpyridine/lanthanide supramolecular nanofiber

Multi-color and white light luminescence materials based on supramolecular assemblies are attractive because of their potential applications in advanced light-emitting material. Herein, a cucurbit[8]uril-enhanced lanthanide luminescent supramolecular asse

Arylene-vinylene terpyridine conjugates: Highly sensitive, reusable and simple fluorescent probes for the detection of nitroaromatics

A series of highly emissive arylene-vinylene conjugated 4′-(4-{2-[aryl]-ethenyl}phenyl)-2,2′:6′,2′′-terpyridines (aryl = 4-methylphenyl, 4-fluorophenyl, 1-naphthyl, and 9-anthralyl in P1-P4 respectively) have been explored for the detection of nitroaromat

Kinetics and the potential well in electrochemical hydrogen evolution by [Co(4-tolyl-tpy)2]2+

The ligand 4-tolyl-tpy [4-tolyl-tpy = 2,6-di(pyridin-2-yl)-4-p-tolylpyridine] and the corresponding cobalt complexes like [Co(4-tolyl-tpy)2]Cl2 and [Co(4-tolyl-tpy)2]Br3 has been synthesized and characterized by

A Cu(II) MOF with a flexible bifunctionalised terpyridine as an efficient catalyst for the single-pot hydrocarboxylation of cyclohexane to carboxylic acid in water/ionic liquid medium

The copper(ii) metal-organic framework (MOF) [Cu(η-1κN,N′,N′′:2κO,O′-L)(NO3)]n (1) [L = 4-((4-([2,2′:6′,2′′-terpyridin]-4′-yl)benzyl)oxy)benzoate] has been synthesized from a flexible bifunctionalised terpyridine species (HL). It was characterized by elemental, FT-IR, powder and single crystal X-ray diffraction analyses. Single crystal X-ray crystallography of 1 shows a 1D polymeric architecture, whose topological analysis illustrates a uninodal (2)-connected net having topological type 2C1. 1 shows good catalytic activity and selectivity towards the hydrocarboxylation of cyclohexane to cyclohexanecarboxylic acid in water/acetonitrile or water/ionic liquid [BMPyr][NTf2] [BMPyr = 1-butyl-1 methylpyrrolidinium; NTf2 = bis(trifluoromethanesulfonyl)imide] medium. It can be recycled and reused without any significant loss of catalytic efficiency. This study provides the first example of an efficient alkane hydrocarboxylation to carboxylic acid, in an ionic liquid and under mild conditions.

Synthesis of 4′-substituted-2,2′;6′,2″-terpyridine Ru(II) complexes electrochemical, fluorescence quenching and antibacterial studies

Three new Ru(II) terpyridine complexes viz. [Ru(BBtpy)2](PF6)2 [Ru(L1)] (BBtpy?=?4′-(4-benzyloxybenzaldehyde)-2,2′:6′,2″-terpyridine), [Ru(BMBtpy)2](PF6)2 [Ru(L2)] (BMBtpy?=?4′-(4-benzyloxy

Design and synthesis of dual probes for detection of metal ions by LALDI MS and fluorescence: Application in Zn(II) imaging in cells

A Label-Assisted Laser Desorption/Ionization (LALDI) technique has recently been applied to the detection of metal ions through a time of flight (TOF) mass spectrometric measurement. In this paper, we report the synthesis of two terpyridine based ligands

Understanding the molecular orientation growth on a nanometer scale and adjustable electron transition performance of a terpyridyl derivative under different external environments

In this study, a terpyridyl derivative 2-(6-(pyridin-2-yl)-4-(4-((E)-2-(pyridin-4-yl)-vinyl)phenyl)pyridin-2-yl)pyridine (abbreviated as PYTPY) has been designed and prepared with an A-π-A architecture (A = electron acceptor), whose spontaneous aggregatio