89972-77-0

Basic information

• Product Name: 4'-(4-METHYLPHENYL)-2,2':6',2''-TERPYRIDINE
• Synonyms: 4'-(4-METHYLPHENYL)-2,2':6',2''-TERPYRIDINE;4''-(4-METHYLPHENYL)-2,2'':6'',2''-TERPYRIDINE 98%;4-(4-methylphenyl)-2,6-bis(2-pyridyl)pyridine;4-(4-methylphenyl)-2,6-di(pyridin-2-yl)pyridine;2-(6-(pyridin-2-yl)-4-p-tolylpyridin-2-yl)pyridine
• CAS NO: 89972-77-0
• Molecular Formula: C₂₂H₁₇N₃
• Molecular Weight: 323.39
• Product Categories: C9 to C46;Heterocyclic Building Blocks;Pyridines
• Mol File: 89972-77-0.mol
• Article Data: 61

Chemical Properties

• Melting Point: 167-170°C
• Boiling Point: 484.6 °C at 760 mmHg
• Flash Point: 211.5 °C
• Appearance: /
• Density: 1.149 g/cm³
• Storage Temp.: Inert atmosphere,Room Temperature
• PKA: 4.62±0.22(Predicted)
• CAS DataBase Reference: 4'-(4-METHYLPHENYL)-2,2':6',2''-TERPYRIDINE(CAS DataBase Reference)
• NIST Chemistry Reference: 4'-(4-METHYLPHENYL)-2,2':6',2''-TERPYRIDINE(89972-77-0)
• EPA Substance Registry System: 4'-(4-METHYLPHENYL)-2,2':6',2''-TERPYRIDINE(89972-77-0)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39-36
• WGK Germany: 3
• RTECS: YT8450000
• Hazardous Substances Data: 89972-77-0(Hazardous Substances Data)

Usage

Uses

4′-(4-Methylphenyl)-2,2′:6′,2′′-terpyridine may be used as a ligand in the synthesis of:terpyridine Ru(II) complexesterpyridine based Cd(II) and Hg(II) complexesheterobimetallic Ru(II)-Os(II) complexes

General Description

4′-(4-Methylphenyl)-2,2′:6′,2′′-terpyridine is a tridentate oligopyridine ligand. Its crystalline structure has been investigated.

Upstream product

• 26482-00-8 1-(2-oxo-2-(2-pyridyl)ethyl)pyridinium iodide 
• 158014-83-6 (E)‐1‐(pyridin‐2‐yl)‐3‐(p‐tolyl)prop‐2‐en‐1‐one 
• 1122-62-9 2-acetylpyridine 
• 104-87-0 4-methyl-benzaldehyde 
• 92206-38-7 ammonium acetate 
• 17084-13-8 potassium hexafluorophosphate 
• 24582-66-9 1-(2-pyridyl)-3-(4-tolyl)propen-1-one 
• 209114-52-3 1,5-di(2-pyridinyl)-3-p-tolylpentane-1,5-dione 

Downstream Products

• 89972-78-1 4'-(4-bromomethylphenyl)-2,2':6',2''-terpyridine 
• 227949-62-4 trichloro(4'-(4-tolyl)-2,2':6',2''-terpyridine)iridium(III) 
• 138645-44-0 Os(tterpy)2⁽²⁺⁾ 
• 121810-59-1 [Ru(4'-p-tolyl-2,2':6',2''-terpyridine)2](2+) 
• 152385-99-4 4'-(p-methylphenyl)-2,2':6',2''-terpyridine platinum(II) chloride 
• 727721-37-1 chloro[4'-(4-methylphenyl)-2,2':6',2''-terpyridine]platinum(II) chloride 
• 868587-92-2 [Mn(4'-(4-methylphenyl)-2,2':6',2''-terpyridine)Cl₂] 
• 609810-65-3 trans-[RuCl₂(S-dimethylsulfoxid)(4'-(4-methylphenyl)-2,2':6',2''-terpyridin)] 
• 777935-95-2 chloro(tolylterpyridine)copper(II) chloride 

Relevant articles and documents

Orange Fluorescent Ru(III) Complexes Based on 4′-Aryl Substituted 2,2′:6′,2″-Terpyridine for OLEDs Application

A series of ruthenium (III) complexes of the formulae [Ru(4-Mephtpy)2]Cl3(1) [Ru(L1)], [Ru(3,4,5-tmphtpy)2]Cl3(2) [Ru(L2)], and [Ru(4-thptpy)2]Cl3(3) [Ru(L3

Complexes of a [2]rotaxane ligand with terminal terpyridine groups

Permanently interlocked [2]rotaxane ligands can be created by capping a pyridine terminated [2]pseudorotaxane with terpyridine containing stoppers. The robust nature of the resulting [2]rotaxane ligand allows coordination to inert metals such as Ru(ii) no

Arylene-vinylene terpyridine conjugates: Highly sensitive, reusable and simple fluorescent probes for the detection of nitroaromatics

A series of highly emissive arylene-vinylene conjugated 4′-(4-{2-[aryl]-ethenyl}phenyl)-2,2′:6′,2′′-terpyridines (aryl = 4-methylphenyl, 4-fluorophenyl, 1-naphthyl, and 9-anthralyl in P1-P4 respectively) have been explored for the detection of nitroaromat

A Cu(II) MOF with a flexible bifunctionalised terpyridine as an efficient catalyst for the single-pot hydrocarboxylation of cyclohexane to carboxylic acid in water/ionic liquid medium

The copper(ii) metal-organic framework (MOF) [Cu(η-1κN,N′,N′′:2κO,O′-L)(NO3)]n (1) [L = 4-((4-([2,2′:6′,2′′-terpyridin]-4′-yl)benzyl)oxy)benzoate] has been synthesized from a flexible bifunctionalised terpyridine species (HL). It was characterized by elemental, FT-IR, powder and single crystal X-ray diffraction analyses. Single crystal X-ray crystallography of 1 shows a 1D polymeric architecture, whose topological analysis illustrates a uninodal (2)-connected net having topological type 2C1. 1 shows good catalytic activity and selectivity towards the hydrocarboxylation of cyclohexane to cyclohexanecarboxylic acid in water/acetonitrile or water/ionic liquid [BMPyr][NTf2] [BMPyr = 1-butyl-1 methylpyrrolidinium; NTf2 = bis(trifluoromethanesulfonyl)imide] medium. It can be recycled and reused without any significant loss of catalytic efficiency. This study provides the first example of an efficient alkane hydrocarboxylation to carboxylic acid, in an ionic liquid and under mild conditions.

Design and synthesis of dual probes for detection of metal ions by LALDI MS and fluorescence: Application in Zn(II) imaging in cells

A Label-Assisted Laser Desorption/Ionization (LALDI) technique has recently been applied to the detection of metal ions through a time of flight (TOF) mass spectrometric measurement. In this paper, we report the synthesis of two terpyridine based ligands

Cobalt bis(2-ethylhexanoate) and terpyridine derivatives as catalysts for the hydrosilylation of olefins

A simple method for the hydrosilylation of olefins by using air-stable cobalt catalysts is developed. The catalyst system is composed of simple, cheap, and readily available cobalt(II) salts and well-defined terpyridine derivatives as cocatalysts or ligands, and the hydrosilylation processes can be processed smoothly under mild conditions without either Grignard reagents or NaHBEt3 as activator.

Electron-accepting carborane viologen and iron based-supramolecular polymers for electrochromism and enhanced photocatalytic hydrogen evolution

Highly electron-accepting viologen derivatives, o-carborane viologens (CbV2+), and their iron based-supramolecular polymers (FeSPs) with tunable optoelectronic properties have been reported. Carborane viologens show excellent electron redox properties wit