C₂₇H₂₃NO₇

Base Information

Chemical Name:C₂₇H₂₃NO₇
CAS No.:1402931-90-1
Molecular Formula:C₂₇H₂₃NO₇
Molecular Weight:473.482
Hs Code.:

C<sub>27</sub>H<sub>23</sub>NO<sub>7</sub>

Synonyms:C₂₇H₂₃NO₇

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Chemical Property of C₂₇H₂₃NO₇

Chemical Property:

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Technology Process of C₂₇H₂₃NO₇

There total 15 articles about C₂₇H₂₃NO₇ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 960365-65-5
(1R,2R,3S,3aR,8bS)-methyl 1,6,8b-trihydroxy-8-methoxy-3a-(4-methoxyphenyl)-3-phenyl-2,3,3a,8b-tetrahydro-1H-benzo[b]-cyclopenta[d]furan-2-carboxylate

: 1402931-90-1
C₂₇H₂₃NO₇

Guidance literature:: Multi-step reaction with 3 steps

1.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 0.82 h / -10 °C / Inert atmosphere

2.1: 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾ / 1-methyl-pyrrolidin-2-one / 20 h / 98 - 104 °C / Inert atmosphere

3.1: lithium hydroxide / methanol; water / 2 h / 50 °C / Inert atmosphere

3.2: pH 1 - 2 / Inert atmosphere

With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; N-ethyl-N,N-diisopropylamine; lithium hydroxide; In 1-methyl-pyrrolidin-2-one; methanol; dichloromethane; water;
DOI:10.1021/jm3011542

Reference yield:

: 1402931-75-2
(1R,2R,3S,3aR,8bS)-methyl 6-cyano-1,8b-dihydroxy-8-methoxy-3a-(4-methoxyphenyl)-3-phenyl-2,3,3a,8b-tetrahydro-1H-benzo[b]-cyclopenta[d]furan-2-carboxylate

: 1402931-90-1
C₂₇H₂₃NO₇

Guidance literature:: (1R,2R,3S,3aR,8bS)-methyl 6-cyano-1,8b-dihydroxy-8-methoxy-3a-(4-methoxyphenyl)-3-phenyl-2,3,3a,8b-tetrahydro-1H-benzo[b]-cyclopenta[d]furan-2-carboxylate; With lithium hydroxide; In methanol; water; at 50 ℃; for 2h; Inert atmosphere;

With hydrogenchloride; In methanol; water; pH=1 - 2; Inert atmosphere;
DOI:10.1021/jm3011542

Reference yield:

: [2-[4-benzyloxy-2-methoxy-6-(4-methoxybenzoyl)oxyphenyl]-2-oxoethyl] 4-methoxybenzoate

: 1402931-90-1
C₂₇H₂₃NO₇

Guidance literature:: Multi-step reaction with 9 steps

1.1: lithium hexamethyldisilazane / tetrahydrofuran / 2 h / -70 - -20 °C / Inert atmosphere

2.1: sulfuric acid; acetic acid / 20 h / 20 °C / Inert atmosphere

3.1: water; sodium hydroxide / ethanol / 1 h / 80 °C / Inert atmosphere

4.1: methanol; dichloromethane; acetonitrile / 10 h / 0 - 5 °C / Inert atmosphere; UV-irradiation

4.2: 1 h / 60 °C / Inert atmosphere

4.3: 48 h / Inert atmosphere

5.1: 5%-palladium/activated carbon; hydrogen / tetrahydrofuran / 18 h / 20 °C / Inert atmosphere

6.1: ChiralPak AD-H / ethanol / Inert atmosphere; Supercritical conditions; Resolution of racemate

7.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 0.82 h / -10 °C / Inert atmosphere

8.1: 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾ / 1-methyl-pyrrolidin-2-one / 20 h / 98 - 104 °C / Inert atmosphere

9.1: lithium hydroxide / methanol; water / 2 h / 50 °C / Inert atmosphere

9.2: pH 1 - 2 / Inert atmosphere

With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; sulfuric acid; 5%-palladium/activated carbon; water; hydrogen; acetic acid; N-ethyl-N,N-diisopropylamine; sodium hydroxide; lithium hydroxide; lithium hexamethyldisilazane; In tetrahydrofuran; 1-methyl-pyrrolidin-2-one; methanol; ethanol; dichloromethane; water; acetonitrile; 1.1: |Baker-Venkataraman Rearrangement;
DOI:10.1021/jm3011542