[5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

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Chemical Name:[5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)
CAS No.:866321-84-8
Molecular Formula:C₆₀H₆₄N₄O₄Zn
Molecular Weight:970.583
Hs Code.:

Synonyms:[5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

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Chemical Property of [5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

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Technology Process of [5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

There total 1 articles about [5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: [5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-(hydroxymethyl)phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

: 36239-09-5
ethyl chlorocarbonylacetate

: 866321-84-8
[5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

Guidance literature:: With triethyl amine; In dichloromethane; ClCOCH2CO3C2H5 was added to a soln. of complex and triethylamine in dry CH2Cl2 at 0°C, the mixt. was stirred for 1 h at 25°C; CHCl3 was added followed by H2O, the organic layer was washed with H2O, satd. aq. NaCl, dried (Na2SO4), evapd. in vac.; flash chromy. (silica gel; cyclohexane/CH2Cl2 1:1, 1% v/v (C2H5)3N), pptn. from CHCl3 by addn. of methanol/H2O 9:1;
DOI:10.1002/hlca.200590144

Reference yield: 45.0%

: 866321-84-8
[5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

: 99685-96-8,161105-99-3,161106-00-9,111138-12-6,133318-63-5,134053-11-5,134931-35-4,134931-36-5,139703-76-7,145633-27-8,175414-73-0,175414-74-1,175414-75-2,175519-12-7,175519-13-8,175519-14-9,175519-15-0,136376-46-0,144906-37-6,144906-38-7,151767-00-9,152882-97-8,152882-98-9,152882-99-0,153062-34-1,154171-74-1,154171-75-2,154333-99-0,154334-00-6,154397-63-4,154460-59-0,199456-56-9,108739-25-9,120329-57-9,120329-58-0
fullerene-C₆₀

: [5,15-bis[3,5-di(tert-butyl)phenyl]-10-[3-([[(3'-ethoxycarbonyl)-3'H-cyclopropa[1,9](C60-I(h))[5,6]fullerene-3'-ylcarbonyl]oxy]methyl)phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; I₂; In toluene; N2 atm.; 1,8-diazabicyclo-compound was added dropwise to a soln. of complex, C60 and I2 in dry and deoxygenated toluene, 1.5 h; filtered through a short plug (silica gel, toluene), flash chromy. (silica gel; cyclohexane/toluene 8:2 -> toluene, 1% v/v (C2H5)3N), evapd. in vac., pptn. from CHCl3 by addn. of methanol;
DOI:10.1002/hlca.200590144