(+/-)-(1S,3S)-ethyl-3-(tert.-butyldimethylsilyloxy)methyl-5-oxocyclohexylcarboxylate

Base Information

Chemical Name:(+/-)-(1S*,3S*)-ethyl-3-(tert.-butyldimethylsilyloxy)methyl-5-oxocyclohexylcarboxylate
CAS No.:123559-34-2
Molecular Formula:C₁₆H₃₀O₄Si
Molecular Weight:314.497
Hs Code.:

Synonyms:(+/-)-(1S*,3S*)-ethyl-3-(tert.-butyldimethylsilyloxy)methyl-5-oxocyclohexylcarboxylate

Suppliers and Price of (+/-)-(1S*,3S*)-ethyl-3-(tert.-butyldimethylsilyloxy)methyl-5-oxocyclohexylcarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (+/-)-(1S*,3S*)-ethyl-3-(tert.-butyldimethylsilyloxy)methyl-5-oxocyclohexylcarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (+/-)-(1S*,3S*)-ethyl-3-(tert.-butyldimethylsilyloxy)methyl-5-oxocyclohexylcarboxylate

There total 2 articles about (+/-)-(1S*,3S*)-ethyl-3-(tert.-butyldimethylsilyloxy)methyl-5-oxocyclohexylcarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 123559-33-1
(+/-)-(1S*,3S*)-ethyl-3-hydroxymethyl-5-oxocyclohexylcarboxylate

: 18162-48-6
tert-butyldimethylsilyl chloride

: 123559-34-2
(+/-)-(1S*,3S*)-ethyl-3-(tert.-butyldimethylsilyloxy)methyl-5-oxocyclohexylcarboxylate

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; for 20h; Ambient temperature;
DOI:10.1016/0040-4020(89)80137-1

Reference yield:

: 123559-32-0
(+/-)-(1R*,4S*,6S*,8R*)-1-ethoxy-2-oxatricyclo<4.2.1.0^4,8>-nonan-7-one dimethylketal

: 123559-34-2
(+/-)-(1S*,3S*)-ethyl-3-(tert.-butyldimethylsilyloxy)methyl-5-oxocyclohexylcarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 55 percent / 1percent aq.HCl / ethanol / 15 h / Heating

2: 52 percent / imidazole / dimethylformamide / 20 h / Ambient temperature

With 1H-imidazole; hydrogenchloride; In ethanol; N,N-dimethyl-formamide;
DOI:10.1016/0040-4020(89)80137-1