N-cyano-S-methyl-S-phenylsulfilimine

Base Information

• Chemical Name: N-cyano-S-methyl-S-phenylsulfilimine
• CAS No.: 946826-90-0
• Molecular Formula: C₈H₈N₂S
• Molecular Weight: 164.231
• Mol file: 946826-90-0.mol

Synonyms:N-cyano-S-methyl-S-phenylsulfilimine

Chemical Property of N-cyano-S-methyl-S-phenylsulfilimine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-cyano-S-methyl-S-phenylsulfilimine

There total 3 articles about N-cyano-S-methyl-S-phenylsulfilimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

CYANAMID (420-04-2) + methyl-phenyl-thioether (100-68-5) → N-(methyl(phenyl)-λ4-sulfanylidene)cyanamide (946826-90-0)

Guidance literature:

With tetramethyl ammonium acetate; In methanol; acetonitrile; at 20 ℃; Electrochemical reaction;

DOI:10.1002/anie.202109033

Reference yield: 93.0%

CYANAMID (420-04-2) + methyl-phenyl-thioether (100-68-5) → N-cyano-S-methyl-S-phenylsulfilimine (946826-90-0)

Guidance literature:

With [bis(acetoxy)iodo]benzene; In acetonitrile; at 0 ℃;

DOI:10.1021/ol071302+

Reference yield:

iodobenzene (591-50-4) → N-(methyl(phenyl)-λ4-sulfanylidene)cyanamide (946826-90-0)

Guidance literature:

Multi-step reaction with 2 steps

1: copper(l) iodide; zinc diacetate / 135 °C / Sealed tube

2: [bis(acetoxy)iodo]benzene / acetonitrile

With copper(l) iodide; [bis(acetoxy)iodo]benzene; zinc diacetate; In acetonitrile;

DOI:10.1002/adsc.201500636

upstream raw materials:

CYANAMID

methyl-phenyl-thioether

iodobenzene

Downstream raw materials:

N-[methyl(oxo)(phenyl)-λ⁶-sulfanylidene]cyanamide

S-methyl-S-phenylsulfoximine

N-(trifluoroacetyl)-S-methyl-S-phenylsulfoximine