(2R,3S)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl 2-carbomethoxyethyl sulfide

Base Information

Chemical Name:(2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl 2-carbomethoxyethyl sulfide
CAS No.:107036-29-3
Molecular Formula:C₃₃H₅₄O₄SSi₂
Molecular Weight:603.026
Hs Code.:

Synonyms:(2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl 2-carbomethoxyethyl sulfide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl 2-carbomethoxyethyl sulfide

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Technology Process of (2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl 2-carbomethoxyethyl sulfide

There total 1 articles about (2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl 2-carbomethoxyethyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.4%

: 104946-98-7
(2R*,3S*)-2,3-bis<4-<(tert-butyldimethylsilyl)oxy>phenyl>-1-pentanethiol

: 292638-85-8,9003-21-8,96-33-3
acrylic acid methyl ester

: 107036-29-3
(2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl 2-carbomethoxyethyl sulfide

Guidance literature:: With sodium methylate; In 1,4-dioxane; at 45 ℃; for 1h;
DOI:10.1021/jm00388a015

Reference yield: 60.6%

: 107036-29-3
(2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl 2-carbomethoxyethyl sulfide

: 107036-30-6
(2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl 3-hydroxypropyl sulfide

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; for 0.333333h;
DOI:10.1021/jm00388a015

Reference yield:

: 107036-29-3
(2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl 2-carbomethoxyethyl sulfide

: 107036-13-5
(2R*,3S*)-2,3-bis(4-hydroxyphenyl)pentyl 3-(N,N-dimethylamino)propyl sulfide

Guidance literature:: Multi-step reaction with 4 steps

1: 60.6 percent / LiAlH₄ / tetrahydrofuran / 0.33 h

2: 93 percent / Et₃N / tetrahydrofuran / 0.33 h

3: 52.5 percent / tetrahydrofuran / 20 h / Heating

4: 68.5 percent / KF, 18-crown-6 / tetrahydrofuran; methanol / 0.5 h

With potassium fluoride; lithium aluminium tetrahydride; 18-crown-6 ether; triethylamine; In tetrahydrofuran; methanol;
DOI:10.1021/jm00388a015