Ru₃(CO)8((C₆H₅)2PCH₂P(C₆H₅)2)2*2(CH₃)2CO

Base Information

• Chemical Name: Ru₃(CO)8((C₆H₅)2PCH₂P(C₆H₅)2)2*2(CH₃)2CO
• CAS No.: 77611-27-9
• Molecular Formula: 2C₃H₆O*C₅₈H₄₄O₈P₄Ru₃
• Molecular Weight: 1412.25
• Mol file: 77611-27-9.mol

Synonyms:Ru₃(CO)8((C₆H₅)2PCH₂P(C₆H₅)2)2*2(CH₃)2CO

Chemical Property of Ru₃(CO)8((C₆H₅)2PCH₂P(C₆H₅)2)2*2(CH₃)2CO

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru₃(CO)8((C₆H₅)2PCH₂P(C₆H₅)2)2*2(CH₃)2CO

There total 4 articles about Ru₃(CO)8((C₆H₅)2PCH₂P(C₆H₅)2)2*2(CH₃)2CO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.7%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + bis-diphenylphosphinomethane (2071-20-7) → octacarbonylbis(μ-bis(diphenylphosphino)methane)triruthenium (77611-27-9,82731-34-8)

Guidance literature:

In xylene; (Ar); stirring (4 h, heating to 65°C), evaporation; chromatography (silica gel column, eluted (hexane/CH2Cl2)), recrystalization (CH2Cl2/hexane);

DOI:10.1016/S1381-1169(99)00196-X

Reference yield: 33.0%

Ru3(CO)10(μ-bis(diphenylphosphino)methane) (64364-79-0) + (diphenylphosphinomethyl)diphenylphosphine selenide (23176-19-4) + water (7732-18-5) → octacarbonylbis(μ-bis(diphenylphosphino)methane)triruthenium (77611-27-9,82731-34-8) + [Ru3(CO)7(μ3-CO)(μ3-Se)(μ-bis(diphenylphosphino)methane)] + [Ru3(CO)5(μ3-CO)(μ3-Se)(μ-bis(diphenylphosphino)methane)2] + [Ru3(CO)6(μ3-CO)(μ3-Se)(μ-bis(diphenylphosphino)methane)(η1-bis(diphenylphosphino)methane monooxide)]

Guidance literature:

In tetrahydrofuran; (N2); Ru cluster and ligand refluxed in THF for 2 h; evapd. (vac.), dissolved in CH2Cl2, chromd. (TLC on silica gel, cyclohexane/CH2Cl2), crystd. (CH2Cl2/hexane, 4°C); elem. anal.;

DOI:10.1016/j.jorganchem.2004.08.015

Reference yield: 12.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + bis-diphenylphosphinomethane (2071-20-7) → Ru3(CO)10((C6H5)2PCH2P(C6H5)2)*C6H5CH3 + Ru3(PC6H5)(CHP(C6H5)2)(CO)7((C6H5)2PCH2P(C6H5)2) + octacarbonylbis(μ-bis(diphenylphosphino)methane)triruthenium (77611-27-9,82731-34-8)

Guidance literature:

In cyclohexane; Ru3(CO)12 and dppm in 1:2 molar ratio were heated in refluxing cyclohexane for 16 h under N2, reaction was monitored by IR spectroscopy; 9% of the starting Ru3(CO)12 was recovered unchanged; sepd. by chromy. over alumina, eluent light petroleum for Ru3(CO)10(dppm) (recrystd. from PhMe/light petroleum to give a PhMe solvate) and 95/5Et2O/C6H6 for Ru3(CO)8(dppm)2, Ru3(PPh)(μ-CHPPh2)(CO)7(dppm) pptd. from the reaction mixt.;

DOI:10.1016/0022-328X(83)85174-2

upstream raw materials:

dodecacarbonyl-triangulo-triruthenium

bis-diphenylphosphinomethane

nonacarbonyl(μ-bis(diphenylphosphino)methane)(η1-bis(diphenylphosphino)methane)triruthenium

Ru3(CO)10(μ-bis(diphenylphosphino)methane)

Downstream raw materials:

[Ru3(μ-bis(diphenylphosphino)methane)2(CO)8(μ-CuNCCH3)][BF4]

Ru3(μ-bis(diphenylphosphino)methane)2(CO)8(μ-Hg(O2CCF3)2)2*2C4H10O

[Ru3(μ-bis(diphenylphosphino)methane)2(CO)8(μ-H)(O2CCF3)*HOCCF3]

Ru₃(CO)7P(C₆H₅)CHP(C₆H₅)2(C₆H₅)2PCH₂P(C₆H₅)2