diphenyl 3,4-di-O-benzyl-2-deoxy-2-fluoro-α-D-gluco-hexodialdo-1,5-pyranosyl phosphate

Base Information

Chemical Name:diphenyl 3,4-di-O-benzyl-2-deoxy-2-fluoro-α-D-gluco-hexodialdo-1,5-pyranosyl phosphate
CAS No.:479622-41-8
Molecular Formula:C₃₂H₃₀FO₈P
Molecular Weight:592.558
Hs Code.:

Synonyms:diphenyl 3,4-di-O-benzyl-2-deoxy-2-fluoro-α-D-gluco-hexodialdo-1,5-pyranosyl phosphate

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Chemical Property of diphenyl 3,4-di-O-benzyl-2-deoxy-2-fluoro-α-D-gluco-hexodialdo-1,5-pyranosyl phosphate

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Technology Process of diphenyl 3,4-di-O-benzyl-2-deoxy-2-fluoro-α-D-gluco-hexodialdo-1,5-pyranosyl phosphate

There total 5 articles about diphenyl 3,4-di-O-benzyl-2-deoxy-2-fluoro-α-D-gluco-hexodialdo-1,5-pyranosyl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 479622-40-7
diphenyl 3,4-di-O-benzyl-2-deoxy-2-fluoro-α-D-glucosyl phosphate

: 479622-41-8
diphenyl 3,4-di-O-benzyl-2-deoxy-2-fluoro-α-D-gluco-hexodialdo-1,5-pyranosyl phosphate

Guidance literature:: With 3 A molecular sieve; pyridinium chlorochromate; In dichloromethane; for 1h;
DOI:10.1071/CH02057

Reference yield:

: 65371-87-1
6-O-acetyl-1,5-anhydro-3,4-di-O-benzyl-2-deoxy-D-arabino-hex-1-enitol

: 479622-41-8
diphenyl 3,4-di-O-benzyl-2-deoxy-2-fluoro-α-D-gluco-hexodialdo-1,5-pyranosyl phosphate

Guidance literature:: Multi-step reaction with 4 steps

1: 41 percent / Selectfluor^TM / dimethylformamide; H₂O / 3 h / 20 °C

2: 89 percent / 4-dimethylaminopyridine / CH₂Cl₂ / 1 h / -10 °C

3: 79 percent / guanidine; guanidinium nitrate / methanol / 0.67 h / 0 °C

4: 89 percent / pyridinium chlorochromate; molecular sieves 3 Angstroem / CH₂Cl₂ / 1 h

With dmap; guanidinium nitrate; 3 A molecular sieve; guanidine nitrate; Selectfluor; pyridinium chlorochromate; In methanol; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1071/CH02057

Reference yield:

: 58871-10-6
3,4-di-O-benzyl-D-glucal

: 479622-41-8
diphenyl 3,4-di-O-benzyl-2-deoxy-2-fluoro-α-D-gluco-hexodialdo-1,5-pyranosyl phosphate

Guidance literature:: Multi-step reaction with 5 steps

1: 92 percent / pyridine / 1 h / 20 °C

2: 41 percent / Selectfluor^TM / dimethylformamide; H₂O / 3 h / 20 °C

3: 89 percent / 4-dimethylaminopyridine / CH₂Cl₂ / 1 h / -10 °C

4: 79 percent / guanidine; guanidinium nitrate / methanol / 0.67 h / 0 °C

5: 89 percent / pyridinium chlorochromate; molecular sieves 3 Angstroem / CH₂Cl₂ / 1 h

With pyridine; dmap; guanidinium nitrate; 3 A molecular sieve; guanidine nitrate; Selectfluor; pyridinium chlorochromate; In methanol; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1071/CH02057