4',N-dimethyl-N-(4-methylbenzenesulfonyl)-4-nitrobiphenyl-2-carboxamide

Base Information

Chemical Name:4',N-dimethyl-N-(4-methylbenzenesulfonyl)-4-nitrobiphenyl-2-carboxamide
CAS No.:1369577-37-6
Molecular Formula:C₂₂H₂₀N₂O₅S
Molecular Weight:424.477
Hs Code.:

Synonyms:4',N-dimethyl-N-(4-methylbenzenesulfonyl)-4-nitrobiphenyl-2-carboxamide

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Chemical Property of 4',N-dimethyl-N-(4-methylbenzenesulfonyl)-4-nitrobiphenyl-2-carboxamide

Chemical Property:

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Technology Process of 4',N-dimethyl-N-(4-methylbenzenesulfonyl)-4-nitrobiphenyl-2-carboxamide

There total 5 articles about 4',N-dimethyl-N-(4-methylbenzenesulfonyl)-4-nitrobiphenyl-2-carboxamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1369577-02-5
4'-methyl-4-nitro-N-(4-methylbenzenesulfonyl)biphenyl-2-carboxamide

: 74-88-4
methyl iodide

: 1369577-37-6
4',N-dimethyl-N-(4-methylbenzenesulfonyl)-4-nitrobiphenyl-2-carboxamide

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 3h;
DOI:10.1021/ol3004244

Reference yield:

: 52448-70-1
3-nitro-N-(4-methylbenzenesulfonyl)benzenecarboxamide

: 1369577-37-6
4',N-dimethyl-N-(4-methylbenzenesulfonyl)-4-nitrobiphenyl-2-carboxamide

Guidance literature:: Multi-step reaction with 2 steps

1: silver(I) acetate; palladium diacetate; acetic acid / 96 h / 120 °C / Inert atmosphere

2: potassium carbonate / N,N-dimethyl-formamide / 3 h / 20 °C

With silver(I) acetate; palladium diacetate; potassium carbonate; acetic acid; In N,N-dimethyl-formamide;
DOI:10.1021/ol3004244

Reference yield:

: 121-90-4
m-nitrobenzoic acid chloride

: 1369577-37-6
4',N-dimethyl-N-(4-methylbenzenesulfonyl)-4-nitrobiphenyl-2-carboxamide

Guidance literature:: Multi-step reaction with 3 steps

1: dmap; triethylamine / ethyl acetate; toluene / 1.25 h / 55 °C / Inert atmosphere

2: silver(I) acetate; palladium diacetate; acetic acid / 96 h / 120 °C / Inert atmosphere

3: potassium carbonate / N,N-dimethyl-formamide / 3 h / 20 °C

With dmap; silver(I) acetate; palladium diacetate; potassium carbonate; acetic acid; triethylamine; In ethyl acetate; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ol3004244