{4-[(2E,6E)-8-(tert-Butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyloxy]-phenyl}-phenyl-methanone

Base Information

Chemical Name:{4-[(2E,6E)-8-(tert-Butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyloxy]-phenyl}-phenyl-methanone
CAS No.:196312-05-7
Molecular Formula:C₂₉H₄₀O₃Si
Molecular Weight:464.72
Hs Code.:

Synonyms:{4-[(2E,6E)-8-(tert-Butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyloxy]-phenyl}-phenyl-methanone

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Chemical Property of {4-[(2E,6E)-8-(tert-Butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyloxy]-phenyl}-phenyl-methanone

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Technology Process of {4-[(2E,6E)-8-(tert-Butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyloxy]-phenyl}-phenyl-methanone

There total 4 articles about {4-[(2E,6E)-8-(tert-Butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyloxy]-phenyl}-phenyl-methanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 127586-84-9
8-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-2,6-dimethyl-2(E),6(E)-octadien-1-ol

: 1137-42-4
4-Hydroxybenzophenone

: 196312-05-7
{4-[(2E,6E)-8-(tert-Butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyloxy]-phenyl}-phenyl-methanone

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at -4 ℃;
DOI:10.1016/S0960-894X(97)00342-9

Reference yield:

: 80873-81-0
geraniol tert-butyldimethylsilyl ether

: 196312-05-7
{4-[(2E,6E)-8-(tert-Butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyloxy]-phenyl}-phenyl-methanone

Guidance literature:: Multi-step reaction with 2 steps

1.1: SeO₂; t-BuOOH; salycylic acid / CH₂Cl₂; H₂O; various solvent(s) / 12 h

1.2: 50 percent / NaBH₄ / methanol

2.1: 81 percent / PPh₃; diethylazodicarboxylate / tetrahydrofuran / 20 °C

With tert.-butylhydroperoxide; selenium(IV) oxide; triphenylphosphine; salicylic acid; diethylazodicarboxylate; In tetrahydrofuran; dichloromethane; water;
DOI:10.1021/ja036178d

Reference yield:

: 106-24-1
Geraniol

: 196312-05-7
{4-[(2E,6E)-8-(tert-Butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyloxy]-phenyl}-phenyl-methanone

Guidance literature:: Multi-step reaction with 3 steps

1.1: 100 percent / i-Pr₂NEt / CH₂Cl₂ / 20 °C

2.1: SeO₂; t-BuOOH; salycylic acid / CH₂Cl₂; H₂O; various solvent(s) / 12 h

2.2: 50 percent / NaBH₄ / methanol

3.1: 81 percent / PPh₃; diethylazodicarboxylate / tetrahydrofuran / 20 °C

With tert.-butylhydroperoxide; selenium(IV) oxide; N-ethyl-N,N-diisopropylamine; triphenylphosphine; salicylic acid; diethylazodicarboxylate; In tetrahydrofuran; dichloromethane; water;
DOI:10.1021/ja036178d