Pentacarbonylchlororhenium

Base Information

• Chemical Name: Pentacarbonylchlororhenium
• CAS No.: 14099-01-5
• Molecular Formula: C5Cl O5 Re
• Molecular Weight: 361.712
• Hs Code.: 28369917
• European Community (EC) Number: 237-948-1
• DSSTox Substance ID: DTXSID30161512
• Mol file: 14099-01-5.mol

Synonyms:14099-01-5;Pentacarbonylchlororhenium;Rhenium pentacarbonyl chloride;Pentacarbonylchlororhenium(I);carbon monoxide;chlororhenium;Rheniumpentacarbonylchloride;MFCD00013296;C5ClO5Re;C5-Cl-O5-Re;DTXSID30161512;Pentacarbonylchlororhenium(I), 98%;CS-0111791;FT-0688495;E76407

Chemical Property of Pentacarbonylchlororhenium

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: -0.35050
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive.: Moisture Sensitive
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 361.899178
• Heavy Atom Count: 12
• Complexity: 12

Purity/Quality:

98%,99%, ^*data from raw suppliers

Pentacarbonylchlororhenium ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T
• Statements: 23/24/25-36/37/38
• Safety Statements: 26-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].Cl[Re]
• Uses: Pentacarbonylchlororhenium(I) was used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands a well as to prepare [3]-ferrocenophane complexes. It has also been employed in preparation of a series of mixed-valence compounds of rhenium and iron. These compounds find application in the study of charge-transfer processes.

Technology Process of Pentacarbonylchlororhenium

There total 74 articles about Pentacarbonylchlororhenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

decacarbonyldirhenium(0) (14285-68-8) → rhenium(I) pentacarbonyl chloride (14099-01-5)

Guidance literature:

With sulfuryl dichloride; In dichloromethane; (N2), soln. of the complex treated with SO2Cl2 at room temp. with stirring, stirred for 30 min at room temp.; solvent and excess SO2Cl2 removed under vacuum, washed with ethanol, dried in vacuo, elem. anal.;

DOI:10.1016/0022-328X(86)80417-X

Reference yield: 97.0%

Re((12)CO)5[C(CO2C2H5)C(CO2C2H5)]Re((12)CO)4 → rhenium(I) pentacarbonyl chloride (14099-01-5) + [CH(CO2C2H5)C(CO2C2H5)]Re((12)CO)5

Guidance literature:

With CO; HCl; In hydrogenchloride; hexane; (under N2); the Re-complex is dissolved in hexane, CO is saturated withHCl gas by puring it through aq. HCl soln., this mixt. is dried by a P2O5 column, the dried CO/HCl mixt. is the purged through the complex soln. at 25°C for 3 h; product is sepd. by TLC on silica gel (hexane/CH2Cl2);

Reference yield: 95.0%

decacarbonyldirhenium(0) (14285-68-8) + sodium chloride (7647-14-5) → rhenium(I) pentacarbonyl chloride (14099-01-5)

Guidance literature:

With Oxone; In neat (no solvent); for 0.0833333h; Milling;

DOI:10.1039/c4sc01252f

upstream raw materials:

hydrogenchloride

decacarbonyldirhenium⁽⁰⁾

tris(2,2'-bipyridyl)cobalt(III)

chloride

Downstream raw materials:

tricarbonylchlorobis(tri-p-tolylphosphine)rhenium

hydrogenchloride

trans,mer-[Re(CO)3Cl(PPh₃)2]

trimethyltin(IV)chloride

Refernces

• 1、 Miroslavov, Alexander E.,Britvin, Sergey N.,Braband, Henrik,Alberto, Roger,Stepanova, Ekaterina S.,Shevyakova, Anna P.,Sidorenko, Georgy V.,Lumpov, Alexander A.. "Water-soluble carbonyl complexes of 99Tc(I) and Re(I) with adamantane-cage aminophosphines PTA and CAP". . p. 83 - 89. Retrieved 2019.
• 2、 Marker, Sierra C.,MacMillan, Samantha N.,Zipfel, Warren R.,Li, Zhi,Ford, Peter C.,Wilson, Justin J.. "Photoactivated in Vitro Anticancer Activity of Rhenium(I) Tricarbonyl Complexes Bearing Water-Soluble Phosphines". . p. 1311 - 1331. Retrieved 2018.
• 3、 Fox, Arnold,Malito, John,Poe, Anthony. "Associative Substitution Reactions of *Re(CO)5". . p. 1052 - 1053. Retrieved 1981.
• 4、 D'Alfonso, Giuseppe,Roberto, Dominique,Ugo, Renato,Bianchi, Claudia L.,Sironi, Angelo. "Surface organometallic chemistry: Easy reductive carbonylation of silica-supported [Re(CO)3(OH)]4 to [Re2(CO)10] via silica-anchored [Re(CO)5(OSi≡)] and the thermal behavior of silica-supported [Re2(CO)10]". . p. 2564 - 2572. Retrieved 2000.
• 5、 O'Connor, Joseph M.,Uhrhammer, Roger,Chadha, Raj K.,Tsuie, Barbara,Rheingold, Arnold L.. "Reactivity studies on bimetallic μ-malonyl complexes: cleavage and alkylation chemistry of the malonyl ligand". . p. 143 - 156. Retrieved 1993.
• 6、 Miroslavov,Sidorenko,Tyupina, M. Yu.,Gurzhiy. "[Re(CO)3(bipy)(ClO4)]: Synthesis in a Proton-Donor Solvent, Crystal, and Molecular Structure". . p. 2333 - 2337. Retrieved 2021/02/12.