6-(5-methoxy-2,4-dimethyl-3,6-dioxo cyclohexa-1,4-dienyl)hexyl nitrate

Base Information

• Chemical Name: 6-(5-methoxy-2,4-dimethyl-3,6-dioxo cyclohexa-1,4-dienyl)hexyl nitrate
• CAS No.: 1431987-13-1
• Molecular Formula: C₁₅H₂₁NO₆
• Molecular Weight: 311.335
• Mol file: 1431987-13-1.mol

Synonyms:6-(5-methoxy-2,4-dimethyl-3,6-dioxo cyclohexa-1,4-dienyl)hexyl nitrate

Chemical Property of 6-(5-methoxy-2,4-dimethyl-3,6-dioxo cyclohexa-1,4-dienyl)hexyl nitrate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6-(5-methoxy-2,4-dimethyl-3,6-dioxo cyclohexa-1,4-dienyl)hexyl nitrate

There total 6 articles about 6-(5-methoxy-2,4-dimethyl-3,6-dioxo cyclohexa-1,4-dienyl)hexyl nitrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 15.0%

7-(nitrooxy)heptanoic acid (944916-36-3) + 2-methoxy-3,5-dimethyl-2,5-cyclohexadiene-1,4-dione (3214-57-1) → 6-(5-methoxy-2,4-dimethyl-3,6-dioxo cyclohexa-1,4-dienyl)hexyl nitrate (1431987-13-1)

Guidance literature:

With dipotassium peroxodisulfate; silver nitrate; In water; acetonitrile; at 75 ℃; for 3h;

Reference yield:

1,3-dimethyl-2,4,5-trimethoxybenzene (92421-42-6) → 6-(5-methoxy-2,4-dimethyl-3,6-dioxo cyclohexa-1,4-dienyl)hexyl nitrate (1431987-13-1)

Guidance literature:

Multi-step reaction with 2 steps

1: [bis(acetoxy)iodo]benzene

2: silver nitrate; dipotassium peroxodisulfate / acetonitrile; water / 3 h / 75 °C

With dipotassium peroxodisulfate; [bis(acetoxy)iodo]benzene; silver nitrate; In water; acetonitrile;

Reference yield:

ethyl 7-(nitrooxy)heptanoate (1431987-45-9) → 6-(5-methoxy-2,4-dimethyl-3,6-dioxo cyclohexa-1,4-dienyl)hexyl nitrate (1431987-13-1)

Guidance literature:

Multi-step reaction with 2 steps

1.1: lithium hydroxide / 4 °C

1.2: pH 1

2.1: silver nitrate; dipotassium peroxodisulfate / acetonitrile; water / 3 h / 75 °C

With dipotassium peroxodisulfate; silver nitrate; lithium hydroxide; In water; acetonitrile;

upstream raw materials:

1,3-dimethyl-2,4,5-trimethoxybenzene

ethyl 7-bromoheptanoate

2,6-dimethyl-1,4-benzoquinone

ethyl 7-(nitrooxy)heptanoate