(+)-(2S,2'R,5S)-1'-[5-ethyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-yl]ethanol

Base Information

Chemical Name:(+)-(2S,2'R,5S)-1'-[5-ethyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-yl]ethanol
CAS No.:1092556-10-9
Molecular Formula:C₁₅H₂₀O₄S
Molecular Weight:296.387
Hs Code.:

Synonyms:(+)-(2S,2'R,5S)-1'-[5-ethyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-yl]ethanol

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Chemical Property of (+)-(2S,2'R,5S)-1'-[5-ethyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-yl]ethanol

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Technology Process of (+)-(2S,2'R,5S)-1'-[5-ethyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-yl]ethanol

There total 3 articles about (+)-(2S,2'R,5S)-1'-[5-ethyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-yl]ethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

: 1092556-56-3
(-)-(6S,S(S))-(2E,4E)-5-(p-tolylsulfinyl)octa-2,4-dien-6-ol

: 1092556-60-9
C₁₅H₂₀O₃S

: (+)-(2R,2'S,5S)-1'-[5-ethyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-yl]ethanol

: 1092556-10-9
(+)-(2S,2'R,5S)-1'-[5-ethyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-yl]ethanol

Guidance literature:: (-)-(6S,S(S))-(2E,4E)-5-(p-tolylsulfinyl)octa-2,4-dien-6-ol; With (S,S)-(+)-N,N’-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride; ammonium acetate; dihydrogen peroxide; In methanol; dichloromethane; at 0 - 4 ℃; for 120h; Inert atmosphere;

With camphor-10-sulfonic acid; In dichloromethane; at 20 ℃; for 24h; optical yield given as %de; Inert atmosphere;
DOI:10.1021/jo801803m

Reference yield: 16.0%

: 1092556-62-1
(+)-(6S,S(S))-(2E,4E)-[5-(p-tolylsulfinyl)octa-2,4-dien-6-yloxy]tributylsilane

: 1092556-60-9
C₁₅H₂₀O₃S

: (+)-(2R,2'S,5S)-1'-[5-ethyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-yl]ethanol

: 1092556-10-9
(+)-(2S,2'R,5S)-1'-[5-ethyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-yl]ethanol

Guidance literature:: (+)-(6S,S(S))-(2E,4E)-[5-(p-tolylsulfinyl)octa-2,4-dien-6-yloxy]tributylsilane; With (S,S)-(+)-N,N’-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride; ammonium acetate; dihydrogen peroxide; In methanol; dichloromethane; at 0 - 4 ℃; for 216h; Inert atmosphere;

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 - 20 ℃; for 16h; optical yield given as %de; Further stages; Inert atmosphere;
DOI:10.1021/jo801803m

Reference yield:

: 1092556-56-3
(-)-(6S,S(S))-(2E,4E)-5-(p-tolylsulfinyl)octa-2,4-dien-6-ol

: (+)-(2R,2'S,5S)-1'-[5-ethyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-yl]ethanol

: 1092556-10-9
(+)-(2S,2'R,5S)-1'-[5-ethyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-yl]ethanol

Guidance literature:: (-)-(6S,S(S))-(2E,4E)-5-(p-tolylsulfinyl)octa-2,4-dien-6-ol; With 3-chloro-benzenecarboperoxoic acid; In toluene; at 20 ℃; for 48h; Inert atmosphere;

With camphor-10-sulfonic acid; In toluene; for 22h; optical yield given as %de; Inert atmosphere;
DOI:10.1021/jo801803m