1-{4-chloro-3-[(4-ethyloxyphenyl)(methoxyl)methyl]phenyl}-1-deoxy-α/β-D-glucopyranose

Base Information

Chemical Name:1-{4-chloro-3-[(4-ethyloxyphenyl)(methoxyl)methyl]phenyl}-1-deoxy-α/β-D-glucopyranose
CAS No.:1318794-59-0
Molecular Formula:C₂₂H₂₇ClO₇
Molecular Weight:438.905
Hs Code.:

Synonyms:1-{4-chloro-3-[(4-ethyloxyphenyl)(methoxyl)methyl]phenyl}-1-deoxy-α/β-D-glucopyranose

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Chemical Property of 1-{4-chloro-3-[(4-ethyloxyphenyl)(methoxyl)methyl]phenyl}-1-deoxy-α/β-D-glucopyranose

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Technology Process of 1-{4-chloro-3-[(4-ethyloxyphenyl)(methoxyl)methyl]phenyl}-1-deoxy-α/β-D-glucopyranose

There total 7 articles about 1-{4-chloro-3-[(4-ethyloxyphenyl)(methoxyl)methyl]phenyl}-1-deoxy-α/β-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 461432-22-4
(5-bromo-2-chlorophenyl)(4-ethyloxyphenyl)methanone

: 1318794-59-0
1-{4-chloro-3-[(4-ethyloxyphenyl)(methoxyl)methyl]phenyl}-1-deoxy-α/β-D-glucopyranose

Guidance literature:: Multi-step reaction with 5 steps

1.1: lithium aluminium tetrahydride / tetrahydrofuran / 1 h / Cooling with ice

1.2: pH 2 - 3 / Cooling with ice

2.1: sodium hydride / tetrahydrofuran / 1 h / Cooling with ice

2.2: 20 °C

3.1: n-butyllithium / tetrahydrofuran / 1 h / -78 °C / Sealed flask

3.2: 1 h

4.1: methanesulfonic acid / toluene; tetrahydrofuran / 20 °C

5.1: boron trifluoride diethyl etherate; triethylsilane / dichloromethane / 20 °C / Cooling with ice

With triethylsilane; lithium aluminium tetrahydride; n-butyllithium; methanesulfonic acid; boron trifluoride diethyl etherate; sodium hydride; In tetrahydrofuran; dichloromethane; toluene;

Reference yield:

: 1318794-58-9
methyl 1-{4-chloro-3-[1-(4-ethyloxyphenyl)(methoxy)methyl]phenyl}-α/β-D-glucopyranoside

: 1318794-59-0
1-{4-chloro-3-[(4-ethyloxyphenyl)(methoxyl)methyl]phenyl}-1-deoxy-α/β-D-glucopyranose

Guidance literature:: With triethylsilane; boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; Cooling with ice;

Reference yield:

: 21739-92-4
5-bromo-2-chlorobenzoic acid

: 1318794-59-0
1-{4-chloro-3-[(4-ethyloxyphenyl)(methoxyl)methyl]phenyl}-1-deoxy-α/β-D-glucopyranose

Guidance literature:: Multi-step reaction with 7 steps

1.1: oxalyl dichloride / N,N-dimethyl-formamide / dichloromethane / 20 °C

2.1: aluminum (III) chloride / dichloromethane / 2 h / 0 - 20 °C

2.2: Cooling with ice

3.1: lithium aluminium tetrahydride / tetrahydrofuran / 1 h / Cooling with ice

3.2: pH 2 - 3 / Cooling with ice

4.1: sodium hydride / tetrahydrofuran / 1 h / Cooling with ice

4.2: 20 °C

5.1: n-butyllithium / tetrahydrofuran / 1 h / -78 °C / Sealed flask

5.2: 1 h

6.1: methanesulfonic acid / toluene; tetrahydrofuran / 20 °C

7.1: boron trifluoride diethyl etherate; triethylsilane / dichloromethane / 20 °C / Cooling with ice

With triethylsilane; aluminum (III) chloride; lithium aluminium tetrahydride; n-butyllithium; oxalyl dichloride; methanesulfonic acid; boron trifluoride diethyl etherate; sodium hydride; N,N-dimethyl-formamide; In tetrahydrofuran; dichloromethane; toluene;