C₂₇H₂₃N₅O₆S₂

Base Information

• Chemical Name: C₂₇H₂₃N₅O₆S₂
• CAS No.: 439093-81-9
• Molecular Formula: C₂₇H₂₃N₅O₆S₂
• Molecular Weight: 577.642
• Mol file: 439093-81-9.mol

Synonyms:C₂₇H₂₃N₅O₆S₂

Chemical Property of C₂₇H₂₃N₅O₆S₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₇H₂₃N₅O₆S₂

There total 5 articles about C₂₇H₂₃N₅O₆S₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

10,11-Dihydro-5H-dibenzo[a,d]cyclohepten-5-one (1210-35-1) → C27H23N5O6S2 (439093-81-9)

Guidance literature:

Multi-step reaction with 4 steps

1: 91 percent / hydroxylamine hydrochloride; pyridine / ethanol / 144 h / 100 °C

2: 96 percent / conc. aq. ammonia; ammonium acetate; zinc / ethanol / Heating

3: 92 percent / triethylamine / ethyl acetate / 0.17 h / -20 °C

4: tetrahydrofuran / 4 h / Heating

With pyridine; ammonium acetate; ammonium hydroxide; hydroxylamine hydrochloride; triethylamine; zinc; In tetrahydrofuran; ethanol; ethyl acetate;

DOI:10.1021/jm0111088

Reference yield:

3-nitro-4-chlorosulfonyl chloride (97-08-5) → C27H23N5O6S2 (439093-81-9)

Guidance literature:

Multi-step reaction with 3 steps

1.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -20 °C

1.2: 55 percent / tetrahydrofuran; hexane / 20 h / -20 - 20 °C

2.1: triethylamine; hydrazine monohydrate / tetrahydrofuran / 6 h / 70 °C

3.1: tetrahydrofuran / 4 h / Heating

With n-butyllithium; hydrazine hydrate; triethylamine; In tetrahydrofuran; hexane;

DOI:10.1021/jm0111088

Reference yield:

10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-one oxime (1785-74-6) → C27H23N5O6S2 (439093-81-9)

Guidance literature:

Multi-step reaction with 3 steps

1: 96 percent / conc. aq. ammonia; ammonium acetate; zinc / ethanol / Heating

2: 92 percent / triethylamine / ethyl acetate / 0.17 h / -20 °C

3: tetrahydrofuran / 4 h / Heating

With ammonium acetate; ammonium hydroxide; triethylamine; zinc; In tetrahydrofuran; ethanol; ethyl acetate;

DOI:10.1021/jm0111088

upstream raw materials:

10,11-Dihydro-5H-dibenzo[a,d]cyclohepten-5-one

3-nitro-4-chlorosulfonyl chloride

10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-one oxime

pyrrole-2-carboxyl acid

Refernces