6-(Bromomethyl)-1,1,4,4-Tetramethyl-1,2,3,4-Tetrahydronaphthalene

Base Information

• Chemical Name: 6-(Bromomethyl)-1,1,4,4-Tetramethyl-1,2,3,4-Tetrahydronaphthalene
• CAS No.: 119435-90-4
• Molecular Formula: C15H21 Br
• Molecular Weight: 281.236
• Hs Code.: 2902900000
• DSSTox Substance ID: DTXSID50370821
• Wikidata: Q72448100
• Mol file: 119435-90-4.mol

Synonyms:119435-90-4;6-(Bromomethyl)-1,1,4,4-Tetramethyl-1,2,3,4-Tetrahydronaphthalene;6-(bromomethyl)-1,1,4,4-tetramethyl-2,3-dihydronaphthalene;6-(BROMOMETHYL)-1,2,3,4-TETRAHYDRO-1,1,4,4-TETRAMETHYLNAPHTHALENE;Naphthalene, 6-(bromomethyl)-1,2,3,4-tetrahydro-1,1,4,4-tetramethyl-;SCHEMBL1616186;DTXSID50370821;MFCD01313850;AKOS015902326;FT-0741862;A25876;2-bromomethyl-5,6,7,8-tetrahydro-5,5,8,8-tetramethylnaphthalene;6-(bromomethyl)-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphtalene;6-bromomethyl-1,1,4,4-tetramethyl-1,2,3,4-tetrahydro-naphthalene;6-Bromomethyl-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphthalene;(5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl) bromomethane;6-(bromomethyl)-1,2,3,4-tetrahydro-1,1,4,4-tetramethyl naphthalene;6-(Bromomethyl)-1,2,3,4-tetrahydro-1,1,4,4-tetramethylnaphthalene

Chemical Property of 6-(Bromomethyl)-1,1,4,4-Tetramethyl-1,2,3,4-Tetrahydronaphthalene

Chemical Property:

• Vapor Pressure: 0.000903mmHg at 25°C
• Melting Point: 37 °C
• Boiling Point: 110-112/0.7mm
• Flash Point: 137.4°C
• PSA: 0.00000
• Density: 1.159g/cm³
• LogP: 4.93050
• Storage Temp.: 2-8°C
• XLogP3: 5.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 280.08266
• Heavy Atom Count: 16
• Complexity: 254

Purity/Quality:

97% ^*data from raw suppliers

6-(Bromomethyl)-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphthalene ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(CCC(C2=C1C=CC(=C2)CBr)(C)C)C

Technology Process of 6-(Bromomethyl)-1,1,4,4-Tetramethyl-1,2,3,4-Tetrahydronaphthalene

There total 3 articles about 6-(Bromomethyl)-1,1,4,4-Tetramethyl-1,2,3,4-Tetrahydronaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.5%

1,1,4,4,6-pentamethyl-1,2,3,4-tetrahydronaphthalene (6683-48-3) → (5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-bromomethane (119435-90-4)

Guidance literature:

With N-Bromosuccinimide; dibenzoyl peroxide; In tetrachloromethane; for 2.5h; Heating / reflux;

Reference yield: 55.0%

1,1,4,4,6-pentamethyl-1,4-dihydronaphthalene (167958-79-4) → (5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-bromomethane (119435-90-4)

Guidance literature:

With N-Bromosuccinimide; dibenzoyl peroxide; In tetrachloromethane;

Reference yield:

azobisisobutyronitrile (34241-39-9) + 1,1,4,4,6-pentamethyl-1,2,3,4-tetrahydronaphthalene (6683-48-3) → (5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-bromomethane (119435-90-4)

Guidance literature:

With N-Bromosuccinimide; In 1,2-dichloro-ethane;

upstream raw materials:

1,1,4,4,6-pentamethyl-1,2,3,4-tetrahydronaphthalene

azobisisobutyronitrile

1,1,4,4,6-pentamethyl-1,4-dihydronaphthalene

Downstream raw materials:

2-(4-Carbomethoxyphenyl)-3-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyl)propionic acid

(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl)methyl-triphenyl-phosphonium bromide

St 80

4-[2-(5,6,7,8-Tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl)ethyl]benzoate