ethyl 3-isopropenylbenzoate

Base Information

• Chemical Name: ethyl 3-isopropenylbenzoate
• CAS No.: 105640-23-1
• Molecular Formula: C₁₂H₁₄O₂
• Molecular Weight: 190.242
• Mol file: 105640-23-1.mol

Synonyms:ethyl 3-isopropenylbenzoate

Chemical Property of ethyl 3-isopropenylbenzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ethyl 3-isopropenylbenzoate

There total 4 articles about ethyl 3-isopropenylbenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Isopropenyl acetate (108-22-5) + ethyl 3-bromobenzoate (24398-88-7) → benzoic acid ethyl ester (93-89-0,99341-95-4) + ethyl 3-isopropenylbenzoate (105640-23-1)

Guidance literature:

With [2,2]bipyridinyl; manganese; trifluoroacetic acid; cobalt(II) bromide; In pyridine; N,N-dimethyl-formamide; at 50 ℃;

DOI:10.1002/ejoc.200400897

Reference yield:

3-(1-hydroxy-1-methylethyl)benzoic acid (40912-34-3) → ethyl 3-isopropenylbenzoate (105640-23-1)

Guidance literature:

With hydrogenchloride;

DOI:10.1021/ja01551a052

Reference yield:

8-hydroxy-m-cymene (5208-37-7) → ethyl 3-isopropenylbenzoate (105640-23-1)

Guidance literature:

Multi-step reaction with 2 steps

1: aqueous KMnO₄

2: ethanolic HCl

With hydrogenchloride; potassium permanganate;

DOI:10.1021/ja01551a052

upstream raw materials:

3-(1-hydroxy-1-methylethyl)benzoic acid

Isopropenyl acetate

ethyl 3-bromobenzoate

8-hydroxy-m-cymene

Refernces

• 1、 Amatore, Muriel,Gosmini, Corinne,Perichon, Jacques. "Cobalt-catalyzed vinylation of functionalized aryl halides with vinyl acetates". . p. 989 - 992. Retrieved 2007/10/03.