N-(1-hydroxy-2-phenyl-6,7-dihydro-5H-benzimidazol-4-ylidene)hydroxylamine

Base Information

Chemical Name:N-(1-hydroxy-2-phenyl-6,7-dihydro-5H-benzimidazol-4-ylidene)hydroxylamine
CAS No.:175136-52-4
Molecular Formula:C₁₃H₁₃N₃O₂
Molecular Weight:243.265
Hs Code.:
DSSTox Substance ID:DTXSID50352440
Mol file:175136-52-4.mol

Synonyms:N-(1-hydroxy-2-phenyl-6,7-dihydro-5H-benzimidazol-4-ylidene)hydroxylamine;175136-52-4;1-hydroxy-2-phenyl-4,5,6,7-tetrahydro-1H-benzo[d]imidazol-4-one oxime;CDS1_000137;Maybridge1_002425;Oprea1_044744;Oprea1_836564;CBDivE_012818;DivK1c_001177;(E)-1-hydroxy-2-phenyl-6,7-dihydro-1H-benzo[d]imidazol-4(5H)-one oxime;DTXSID50352440;FT-0607925;4-hydroxyimino-2-phenyl-4,5,6,7-tetrahydro-1h-benzimidazol-1-ol;1-HYDROXY-2-PHENYL-4,5,6,7-TETRAHYDRO-1H-BENZO[D]IMIDAZOL-4-ONEOXIME

Suppliers and Price of N-(1-hydroxy-2-phenyl-6,7-dihydro-5H-benzimidazol-4-ylidene)hydroxylamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
1-Hydroxy-2-phenyl-6,7-dihydro-1H-benzo[d]imidazol-4(5H)-oneoxime 95+%
5g
$ 874.00

American Custom Chemicals Corporation
1-HYDROXY-2-PHENYL-4,5,6,7-TETRAHYDRO-1H-BENZO[D]IMIDAZOL-4-ONE OXIME 95.00%
10G
$ 1598.40

Total 5 raw suppliers

Chemical Property of N-(1-hydroxy-2-phenyl-6,7-dihydro-5H-benzimidazol-4-ylidene)hydroxylamine

Chemical Property:

Vapor Pressure:1.81E-13mmHg at 25°C
Melting Point:270oC
Boiling Point:562.1oC at 760 mmHg
Flash Point:293.7oC
PSA：70.64000
Density:1.42g/cm3
LogP:2.30200
XLogP3:2.5
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:1
Exact Mass:243.100776666
Heavy Atom Count:18
Complexity:328

Purity/Quality:

97% ^*data from raw suppliers

1-Hydroxy-2-phenyl-6,7-dihydro-1H-benzo[d]imidazol-4(5H)-oneoxime 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC2=C(C(=NO)C1)N=C(N2O)C3=CC=CC=C3

Technology Process of N-(1-hydroxy-2-phenyl-6,7-dihydro-5H-benzimidazol-4-ylidene)hydroxylamine

There total 1 articles about N-(1-hydroxy-2-phenyl-6,7-dihydro-5H-benzimidazol-4-ylidene)hydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 10528-54-8
1,2,3-cyclohexanetrione-1,3-dioxime

: 100-52-7
benzaldehyde

: 175136-52-4
4-hydroxyimino-2-phenyl-4,5,6,7-tetrahydro-1H-benzimidazol-1-ol

Guidance literature:: With ammonia; In methanol; at 20 ℃; Cooling;
DOI:10.1134/S1070428017010122

Reference yield:

: 175136-52-4
4-hydroxyimino-2-phenyl-4,5,6,7-tetrahydro-1H-benzimidazol-1-ol

: 2-phenyl-1,5,6,7-tetrahydro-4H-benzimidazol-4-one

Guidance literature:: Multi-step reaction with 2 steps

1.1: hydrogenchloride / water / 80 °C

1.2: pH 6

2.1: chloroacetone; triethylamine / acetone / 24 h / 20 °C

With hydrogenchloride; triethylamine; chloroacetone; In water; acetone;
DOI:10.1134/S1070428017010122