all-cis-5-(1-ethylpropoxy)-4,6-dihydroxycyclohexane-1,3-dicarboxylic acid diethyl ester

Base Information

Chemical Name:all-cis-5-(1-ethylpropoxy)-4,6-dihydroxycyclohexane-1,3-dicarboxylic acid diethyl ester
CAS No.:367252-59-3
Molecular Formula:C₁₇H₃₀O₇
Molecular Weight:346.421
Hs Code.:

Synonyms:all-cis-5-(1-ethylpropoxy)-4,6-dihydroxycyclohexane-1,3-dicarboxylic acid diethyl ester

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Chemical Property of all-cis-5-(1-ethylpropoxy)-4,6-dihydroxycyclohexane-1,3-dicarboxylic acid diethyl ester

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Technology Process of all-cis-5-(1-ethylpropoxy)-4,6-dihydroxycyclohexane-1,3-dicarboxylic acid diethyl ester

There total 6 articles about all-cis-5-(1-ethylpropoxy)-4,6-dihydroxycyclohexane-1,3-dicarboxylic acid diethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 367252-57-1
all-cis-5-(1-ethylpropoxy)-4,6-dimethoxycyclohexane-1,3-dicarboxylic acid diethyl ester

: 367252-59-3
all-cis-5-(1-ethylpropoxy)-4,6-dihydroxycyclohexane-1,3-dicarboxylic acid diethyl ester

Guidance literature:: With chloro-trimethyl-silane; sodium iodide; In acetonitrile; at 40 ℃;
DOI:10.2533/000942904777677605

Reference yield:

: 91-10-1
1,3-dimethoxy-2-hydroxy-benzene

: 367252-59-3
all-cis-5-(1-ethylpropoxy)-4,6-dihydroxycyclohexane-1,3-dicarboxylic acid diethyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: KOtBu / dimethylsulfoxide / 50 °C

2: NBS / dimethylformamide / 0 °C

3: 95 percent / Pd(OAc)2; dppp; KOAc / 20 h / 110 °C

4: 82 percent / H₂ / Ru-Alox / ethyl acetate / 24 h / 60 °C

5: 97 percent / TMSCl; NaI / acetonitrile / 40 °C

With palladium diacetate; N-Bromosuccinimide; chloro-trimethyl-silane; 1,3-bis-(diphenylphosphino)propane; potassium tert-butylate; hydrogen; potassium acetate; sodium iodide; aluminum oxide; ruthenium; In dimethyl sulfoxide; ethyl acetate; N,N-dimethyl-formamide; acetonitrile;
DOI:10.2533/000942904777677605

Reference yield:

: 4358-72-9
methanesulfonic acid 1-ethylpropyl ester

: 367252-59-3
all-cis-5-(1-ethylpropoxy)-4,6-dihydroxycyclohexane-1,3-dicarboxylic acid diethyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: KOtBu / dimethylsulfoxide / 50 °C

2: NBS / dimethylformamide / 0 °C

3: 95 percent / Pd(OAc)2; dppp; KOAc / 20 h / 110 °C

4: 82 percent / H₂ / Ru-Alox / ethyl acetate / 24 h / 60 °C

5: 97 percent / TMSCl; NaI / acetonitrile / 40 °C

With palladium diacetate; N-Bromosuccinimide; chloro-trimethyl-silane; 1,3-bis-(diphenylphosphino)propane; potassium tert-butylate; hydrogen; potassium acetate; sodium iodide; aluminum oxide; ruthenium; In dimethyl sulfoxide; ethyl acetate; N,N-dimethyl-formamide; acetonitrile;
DOI:10.2533/000942904777677605