(E)-3-acetoxy-9-(phenylsulfonyl)-2-methylene-1-(trimethylsilyl)-8-nonene

Base Information

Chemical Name:(E)-3-acetoxy-9-(phenylsulfonyl)-2-methylene-1-(trimethylsilyl)-8-nonene
CAS No.:136276-86-3
Molecular Formula:C₂₁H₃₂O₄SSi
Molecular Weight:408.634
Hs Code.:

Synonyms:(E)-3-acetoxy-9-(phenylsulfonyl)-2-methylene-1-(trimethylsilyl)-8-nonene

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Chemical Property of (E)-3-acetoxy-9-(phenylsulfonyl)-2-methylene-1-(trimethylsilyl)-8-nonene

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Technology Process of (E)-3-acetoxy-9-(phenylsulfonyl)-2-methylene-1-(trimethylsilyl)-8-nonene

There total 4 articles about (E)-3-acetoxy-9-(phenylsulfonyl)-2-methylene-1-(trimethylsilyl)-8-nonene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 136276-87-4
(E)-9-Benzenesulfonyl-2-trimethylsilanylmethyl-nona-1,8-dien-3-ol

: 75-36-5
acetyl chloride

: 136276-86-3
(E)-3-acetoxy-9-(phenylsulfonyl)-2-methylene-1-(trimethylsilyl)-8-nonene

Guidance literature:: With pyridine; dmap; In dichloromethane; at 0 ℃; for 0.666667h; Yield given;
DOI:10.1021/ja00019a036

Reference yield:

: 81790-10-5
(2-bromoallyl)trimethylsilane

: 136276-86-3
(E)-3-acetoxy-9-(phenylsulfonyl)-2-methylene-1-(trimethylsilyl)-8-nonene

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) magnesium, chlorotrimethylsilane, iodine / 1.) THF, reflux, 15 min, 2.) THF, -78 deg C, 40 min

2: pyridine, DMAP / CH₂Cl₂ / 0.67 h / 0 °C

With pyridine; dmap; chloro-trimethyl-silane; iodine; magnesium; In dichloromethane;
DOI:10.1021/ja00019a036

Reference yield:

: 107010-56-0
(E)-7-(phenylsulfonyl)-6-hepten-7-al

: 136276-86-3
(E)-3-acetoxy-9-(phenylsulfonyl)-2-methylene-1-(trimethylsilyl)-8-nonene

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) magnesium, chlorotrimethylsilane, iodine / 1.) THF, reflux, 15 min, 2.) THF, -78 deg C, 40 min

2: pyridine, DMAP / CH₂Cl₂ / 0.67 h / 0 °C

With pyridine; dmap; chloro-trimethyl-silane; iodine; magnesium; In dichloromethane;
DOI:10.1021/ja00019a036