{4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butoxy}-tert-butyl-dimethyl-silane

Base Information

Chemical Name:{4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butoxy}-tert-butyl-dimethyl-silane
CAS No.:333754-76-0
Molecular Formula:C₆₀H₆₆O₇P₂Si
Molecular Weight:989.213
Hs Code.:

{4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butoxy}-<i>tert</i>-butyl-dimethyl-silane

Synonyms:{4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butoxy}-tert-butyl-dimethyl-silane

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Chemical Property of {4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butoxy}-tert-butyl-dimethyl-silane

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Technology Process of {4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butoxy}-tert-butyl-dimethyl-silane

There total 9 articles about {4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butoxy}-tert-butyl-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 4559-70-0
Diphenylphosphine oxide

: 356068-30-9,462109-15-5
[4-(3,3'-bis-chloromethyl-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl)-butoxy]-tert-butyl-dimethyl-silane

: 333754-76-0
{4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butoxy}-tert-butyl-dimethyl-silane

Guidance literature:: With sodium t-butanolate; In tetrahydrofuran;
DOI:10.1016/S0040-4039(00)01923-7

Reference yield:

: 75685-01-7
2,2'-dimethoxy-1,1'-binaphthyl

: 333754-76-0
{4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butoxy}-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 9 steps

1: 80 percent / AlCl₃ / CH₂Cl₂

3: LAH / tetrahydrofuran

4: 91 percent / imidazole / dimethylformamide

5: 61 percent / BuLi / diethyl ether

6: 98 percent / NaBH₄ / methanol

7: Et₃N / CH₂Cl₂

8: LiCl / dimethylformamide

9: 100 percent / NaOtBu / tetrahydrofuran

With 1H-imidazole; sodium tetrahydroborate; lithium aluminium tetrahydride; n-butyllithium; aluminium trichloride; triethylamine; lithium chloride; sodium t-butanolate; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide; 1: Friedel-Crafts acylation;
DOI:10.1016/S0040-4039(00)01923-7

Reference yield:

: 205107-27-3
4-(2,2'-dimethoxy-[1,1']binaphthalenyl-6-yl)-4-oxo-butyric acid ethyl ester

: 333754-76-0
{4-[3,3'-bis-(diphenyl-phosphinoylmethyl)-2,2'-bis-methoxymethoxy-[1,1']binaphthalenyl-6-yl]-butoxy}-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 8 steps

2: LAH / tetrahydrofuran

3: 91 percent / imidazole / dimethylformamide

4: 61 percent / BuLi / diethyl ether

5: 98 percent / NaBH₄ / methanol

6: Et₃N / CH₂Cl₂

7: LiCl / dimethylformamide

8: 100 percent / NaOtBu / tetrahydrofuran

With 1H-imidazole; sodium tetrahydroborate; lithium aluminium tetrahydride; n-butyllithium; triethylamine; lithium chloride; sodium t-butanolate; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)01923-7