C₆₄H₁₁₆O₁₁Si₄

Base Information

Chemical Name:C₆₄H₁₁₆O₁₁Si₄
CAS No.:942505-84-2
Molecular Formula:C₆₄H₁₁₆O₁₁Si₄
Molecular Weight:1173.96
Hs Code.:

C<sub>64</sub>H<sub>116</sub>O<sub>11</sub>Si<sub>4</sub>

Synonyms:C₆₄H₁₁₆O₁₁Si₄

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Chemical Property of C₆₄H₁₁₆O₁₁Si₄

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Technology Process of C₆₄H₁₁₆O₁₁Si₄

There total 23 articles about C₆₄H₁₁₆O₁₁Si₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 942505-84-2
C₆₄H₁₁₆O₁₁Si₄

Guidance literature:: Multi-step reaction with 8 steps

1.1: imidazole; DMAP / dimethylformamide

1.2: O₃ / CH₂Cl₂ / -78 °C

1.3: 85 percent / PPh₃ / CH₂Cl₂

2.1: (-)-Ipc₂BCl; Et₃N / diethyl ether

2.2: 75 percent / diethyl ether / -78 °C

3.1: Me₄NBH(OAc)3; AcOH / acetonitrile / -30 °C

3.2: DDQ; 4 Angstroem molecular sieves / CH₂Cl₂

3.3: 51 percent / 2,6-lutidine / CH₂Cl₂

4.1: 62 percent / BH₃*Me₂S / toluene / 100 °C

5.1: Dess-Martin periodinane / CH₂Cl₂

5.2: PPh₃; Et₃N / CH₂Cl₂ / -78 °C

5.3: 76 percent / n-BuLi / tetrahydrofuran

6.1: n-BuLi / tetrahydrofuran / -20 °C

6.2: tetrahydrofuran / -78 °C

7.1: Dess-Martin periodinane; NaHCO₃ / CH₂Cl₂

8.1: H₂; quinoline / Pd/CaCO₃/Pb / ethanol

With 1H-imidazole; quinoline; dmap; n-butyllithium; dimethylsulfide borane complex; hydrogen; sodium hydrogencarbonate; Dess-Martin periodane; acetic acid; triethylamine; (-)-diisopinocamphenylborane chloride; tetramethylammonium triacetoxyborohydride; Lindlar's catalyst; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; N,N-dimethyl-formamide; toluene; acetonitrile; 5.2: Corey Fuchs alkynylation / 5.3: Corey-Fuchs alkynylation / 7.1: Dess-Martin oxidation / 8.1: Lindlar reduction;
DOI:10.1039/b700827a

Reference yield:

: C₆₄H₁₁₄O₁₁Si₄

: 942505-84-2
C₆₄H₁₁₆O₁₁Si₄

Guidance literature:: With quinoline; hydrogen; Lindlar's catalyst; In ethanol;
DOI:10.1039/b700827a

Reference yield:

: 866021-64-9
(R)-3-(tert-butyldimethylsilanyloxy)-4-{(2S,6R)-6-[2-(tert-butyldimethylsilanyloxy)ethyl]tetrahydropyran-2-yl}butyraldehyde

: 942505-84-2
C₆₄H₁₁₆O₁₁Si₄

Guidance literature:: Multi-step reaction with 7 steps

1.1: (-)-Ipc₂BCl; Et₃N / diethyl ether

1.2: 75 percent / diethyl ether / -78 °C

2.1: Me₄NBH(OAc)3; AcOH / acetonitrile / -30 °C

2.2: DDQ; 4 Angstroem molecular sieves / CH₂Cl₂

2.3: 51 percent / 2,6-lutidine / CH₂Cl₂

3.1: 62 percent / BH₃*Me₂S / toluene / 100 °C

4.1: Dess-Martin periodinane / CH₂Cl₂

4.2: PPh₃; Et₃N / CH₂Cl₂ / -78 °C

4.3: 76 percent / n-BuLi / tetrahydrofuran

5.1: n-BuLi / tetrahydrofuran / -20 °C

5.2: tetrahydrofuran / -78 °C

6.1: Dess-Martin periodinane; NaHCO₃ / CH₂Cl₂

7.1: H₂; quinoline / Pd/CaCO₃/Pb / ethanol

With quinoline; n-butyllithium; dimethylsulfide borane complex; hydrogen; sodium hydrogencarbonate; Dess-Martin periodane; acetic acid; triethylamine; (-)-diisopinocamphenylborane chloride; tetramethylammonium triacetoxyborohydride; Lindlar's catalyst; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; toluene; acetonitrile; 4.2: Corey Fuchs alkynylation / 4.3: Corey-Fuchs alkynylation / 6.1: Dess-Martin oxidation / 7.1: Lindlar reduction;
DOI:10.1039/b700827a