1'-(4-biphenylcarbonyl)-1-bromoferrocene

Base Information

Chemical Name:1'-(4-biphenylcarbonyl)-1-bromoferrocene
CAS No.:263261-10-5
Molecular Formula:C₂₃H₁₇BrFeO
Molecular Weight:445.138
Hs Code.:

Synonyms:1'-(4-biphenylcarbonyl)-1-bromoferrocene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1'-(4-biphenylcarbonyl)-1-bromoferrocene

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Technology Process of 1'-(4-biphenylcarbonyl)-1-bromoferrocene

There total 1 articles about 1'-(4-biphenylcarbonyl)-1-bromoferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: 1293-65-8
1,1'-dibromoferrocene

: 2920-38-9
4-cyano-1,1'-biphenyl

: 263261-10-5
1'-(4-biphenylcarbonyl)-1-bromoferrocene

Guidance literature:: With n-BuLi; In tetrahydrofuran; hexane; byproducts: monobromoferrocene; under N2, 1.6 M hexane soln. of n-BuLi was added to thf soln. of Fe-complex, stirring at 25 °C for 30 min, 1 equiv. of nitrile was added,further 25 min stirring at same temp.; H2O was added, extn. twice with CH2Cl2, extract was dried over Na2SO4, evapd. to dryness in vac., chromy. (neutral alumina II), elution with hexane (di- and monobromoferrocenes were sepd.) then hexane/EtOAc=25:1 mixt.;
DOI:10.1021/om9908884

Reference yield: 61.0%

: 263261-10-5
1'-(4-biphenylcarbonyl)-1-bromoferrocene

: 263261-14-9
1'-(4-biphenylmethyl)-1-bromoferrocene

Guidance literature:: With LiAlH₄; AlCl₃; In diethyl ether; under N2, AlCl3 was added to ethereal soln. of Fe-complex and LiAlH4, stirring for 1 h; H2O was added, ethereal layer was sepd., washed with H2O, dried over MgSO4, solvent was evapd., chromy. (neutral alumina, hexane);
DOI:10.1021/om9908884