5-benzyloxycarbonyl-2-(2-bromo-acetyloxy)-pentandioic acid

Base Information

Chemical Name:5-benzyloxycarbonyl-2-(2-bromo-acetyloxy)-pentandioic acid
CAS No.:872139-37-2
Molecular Formula:C₁₄H₁₅BrO₆
Molecular Weight:359.173
Hs Code.:

Synonyms:5-benzyloxycarbonyl-2-(2-bromo-acetyloxy)-pentandioic acid

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Chemical Property of 5-benzyloxycarbonyl-2-(2-bromo-acetyloxy)-pentandioic acid

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Technology Process of 5-benzyloxycarbonyl-2-(2-bromo-acetyloxy)-pentandioic acid

There total 4 articles about 5-benzyloxycarbonyl-2-(2-bromo-acetyloxy)-pentandioic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: γ-benzyl 2-hydroxy-glutaric acid dicyclohexylamine salt

: 598-21-0
2-Bromoacetyl bromide

: 872139-37-2
5-benzyloxycarbonyl-2-(2-bromo-acetyloxy)-pentandioic acid

Guidance literature:: With triethylamine; In dichloromethane; for 4h; Inert atmosphere;
DOI:10.1021/bm100433c

Reference yield:

: 56-86-0,21675-62-7,23009-64-5,25104-13-6,84960-48-5,25513-46-6
L-glutamic acid

: 872139-37-2
5-benzyloxycarbonyl-2-(2-bromo-acetyloxy)-pentandioic acid

Guidance literature:: Multi-step reaction with 3 steps

1.1: methanesulfonic acid / toluene / 5 h / 30 - 45 °C / Inert atmosphere

2.1: acetic acid; sodium nitrite / water / 4 h / 30 °C / Inert atmosphere

2.2: 0.5 h / Inert atmosphere; Cooling

3.1: triethylamine / dichloromethane / 4 h / Inert atmosphere

With methanesulfonic acid; acetic acid; triethylamine; sodium nitrite; In dichloromethane; water; toluene;
DOI:10.1021/bm100433c

Reference yield:

: 1676-73-9,25014-27-1
L-glutamic acid γ-benzyl ester

: 872139-37-2
5-benzyloxycarbonyl-2-(2-bromo-acetyloxy)-pentandioic acid

Guidance literature:: Multi-step reaction with 2 steps

1.1: acetic acid; sodium nitrite / water / 4 h / 30 °C / Inert atmosphere

1.2: 0.5 h / Inert atmosphere; Cooling

2.1: triethylamine / dichloromethane / 4 h / Inert atmosphere

With acetic acid; triethylamine; sodium nitrite; In dichloromethane; water;
DOI:10.1021/bm100433c