IrOs(H)2(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-) = {IrOs(H)2(CO)3(((C₆H₅)2P)2CH₂)2}BF₄

Base Information

• Chemical Name: IrOs(H)2(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-) = {IrOs(H)2(CO)3(((C₆H₅)2P)2CH₂)2}BF₄
• CAS No.: 132939-86-7
• Molecular Formula: BF₄*C₅₃H₄₆IrO₃OsP₄
• Molecular Weight: 1324.07
• Mol file: 132939-86-7.mol

Synonyms:IrOs(H)2(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-) = {IrOs(H)2(CO)3(((C₆H₅)2P)2CH₂)2}BF₄

Chemical Property of IrOs(H)2(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-) = {IrOs(H)2(CO)3(((C₆H₅)2P)2CH₂)2}BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of IrOs(H)2(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-) = {IrOs(H)2(CO)3(((C₆H₅)2P)2CH₂)2}BF₄

There total 2 articles about IrOs(H)2(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-) = {IrOs(H)2(CO)3(((C₆H₅)2P)2CH₂)2}BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + IrOs(H)2(CO)3((C6H4)C6H5PCH2P(C6H5)2)((C6H5)2PCH2P(C6H5)2) (132959-03-6) → IrOs(H)2(CO)3((C6H5)2PCH2P(C6H5)2)2(1+)*BF4(1-) = {IrOs(H)2(CO)3(((C6H5)2P)2CH2)2}BF4 (132939-86-7)

Guidance literature:

In tetrahydrofuran; diethyl ether; (Ar); added a soln. of B-compound in diethyl ether to stirred slurry of Ir-complex; stirred for 1 h; discarded; washed with hexane; 3 h under vacuo; extracted with CH2Cl2; added Et2O; elem. anal.;

DOI:10.1021/om00051a018

Reference yield:

IrOs(CO)5((C6H5)2PCH2P(C6H5)2)2(1+)*BF4(1-) = {IrOs(CO)5(((C6H5)2P)2CH2)2}BF4 (132959-02-5) → IrOs(H)2(CO)3((C6H5)2PCH2P(C6H5)2)2(1+)*BF4(1-) = {IrOs(H)2(CO)3(((C6H5)2P)2CH2)2}BF4 (132939-86-7)

Guidance literature:

With H₂; In dichloromethane; stirred a soln. of Ir-complex under a stream of H2 for 36 h; evapd. (vac.); (31)P NMR; IR;

DOI:10.1021/om00051a018

Reference yield: 100.0%

IrOs(H)2(CO)3((C6H5)2PCH2P(C6H5)2)2(1+)*BF4(1-) = {IrOs(H)2(CO)3(((C6H5)2P)2CH2)2}BF4 (132939-86-7) + sodium hydride (7646-69-7) → IrOs(H)2(CO)3((C6H4)C6H5PCH2P(C6H5)2)((C6H5)2PCH2P(C6H5)2) (132959-03-6)

Guidance literature:

In tetrahydrofuran; (Ar); added THF to NaH and Ir-complex; stirred vigorously for 1 h; evapd. (vac.); (31)P NMR, IR;

DOI:10.1021/om00051a018

upstream raw materials:

tetrafluoroboric acid diethyl ether

IrOs(H)2(CO)3((C₆H₄)C₆H₅PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂P(C₆H₅)2)

IrOs(CO)5((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-) = {IrOs(CO)5(((C₆H₅)2P)2CH₂)2}BF₄

Downstream raw materials:

IrOs(H)2(CO)3((C₆H₄)C₆H₅PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂P(C₆H₅)2)

IrOs(CO)5((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-) = {IrOs(CO)5(((C₆H₅)2P)2CH₂)2}BF₄

Refernces