[(κ2-(C1,C4)-(C(methoxycarbonyl))4)(iridium)(1,1,1-tris(diphenylphosphinomethyl)ethane)(carbonyl)](tetrafluoroborate)

Base Information

• Chemical Name: [(κ2-(C1,C4)-(C(methoxycarbonyl))4)(iridium)(1,1,1-tris(diphenylphosphinomethyl)ethane)(carbonyl)](tetrafluoroborate)
• CAS No.: 362059-02-7
• Molecular Formula: BF₄*C₅₄H₅₁IrO₉P₃
• Molecular Weight: 1215.94

Synonyms:[(κ2-(C1,C4)-(C(methoxycarbonyl))4)(iridium)(1,1,1-tris(diphenylphosphinomethyl)ethane)(carbonyl)](tetrafluoroborate)

Chemical Property of [(κ2-(C1,C4)-(C(methoxycarbonyl))4)(iridium)(1,1,1-tris(diphenylphosphinomethyl)ethane)(carbonyl)](tetrafluoroborate)

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of [(κ2-(C1,C4)-(C(methoxycarbonyl))4)(iridium)(1,1,1-tris(diphenylphosphinomethyl)ethane)(carbonyl)](tetrafluoroborate)

There total 3 articles about [(κ2-(C1,C4)-(C(methoxycarbonyl))4)(iridium)(1,1,1-tris(diphenylphosphinomethyl)ethane)(carbonyl)](tetrafluoroborate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

carbon monoxide (201230-82-2) + [(κ2-(C1,C4-(C(methoxycarbonyl))4)(iridium)(1,1,1-tris(diphenylphosphinomethyl)ethane)(acetonitrile)](tetrafluoroborate) (362058-93-3) → [(κ2-(C1,C4)-(C(methoxycarbonyl))4)(iridium)(1,1,1-tris(diphenylphosphinomethyl)ethane)(carbonyl)](tetrafluoroborate) (362059-02-7)

Guidance literature:

With H₂O; In dichloromethane; CO2 bubbled through soln. of Ir complex (0.16 mmol) in wet CH2Cl2 for 30min, stirred at room temp. for 24 h under CO; volatiles removed under vac., residue recrystd. from CH2Cl2/Et2O; elem. anal.;

DOI:10.1016/j.ica.2010.07.052

Reference yield: 86.0%

(Ir(CH3C(CH2P(C6H5)2)3)((CCOOCH3)4)(CH3CN))(1+)*BF4(1-)=(Ir(CH3C(CH2P(C6H5)2)3)((CCOOCH3)4)(CH3CN))BF4 (362058-93-3) + carbon monoxide (201230-82-2) → (Ir(CH3C(CH2P(C6H5)2)3)((CCOOCH3)4)(CO))(1+)*BF4(1-)=(Ir(CH3C(CH2P(C6H5)2)3)((CCOOCH3)4)(CO))BF4 (362059-02-7)

Guidance literature:

In not given; react with CO (1 atm);

DOI:10.1021/om0102450

Reference yield:

(CH3C(CH2P(C6H5)2)3)Ir[C(CO2CH3)C(CO2CH3)C(CO2CH3)C(CO2CH3)]Cl → (Ir(CH3C(CH2P(C6H5)2)3)((CCOOCH3)4)(CO))(1+)*BF4(1-)=(Ir(CH3C(CH2P(C6H5)2)3)((CCOOCH3)4)(CO))BF4 (362059-02-7)

Guidance literature:

Multi-step reaction with 2 steps

1: acetonitrile

2: not given

In acetonitrile;

DOI:10.1021/om0102450

upstream raw materials:

(Ir(CH₃C(CH₂P(C₆H₅)2)3)((CCOOCH₃)4)(CH₃CN))⁽¹⁺⁾*BF₄^(1-)=(Ir(CH₃C(CH₂P(C₆H₅)2)3)((CCOOCH₃)4)(CH₃CN))BF₄

carbon monoxide

[(κ2-(C1,C4-(C(methoxycarbonyl))4)(iridium)(1,1,1-tris(diphenylphosphinomethyl)ethane)(acetonitrile)](tetrafluoroborate)

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