Technology Process of 4-[8-(p-toluenesulfonyl)-7-octynyl]-1,2-(methylenedioxy)benzene
There total 8 articles about 4-[8-(p-toluenesulfonyl)-7-octynyl]-1,2-(methylenedioxy)benzene which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
p-tolyl benzeneselenosulfonate; 4-(7-octynyl)-1,2-(methylenedioxy)benzene;
In
chloroform;
for 2h;
UV-irradiation;
With
3-chloro-benzenecarboperoxoic acid;
In
chloroform;
for 0.333333h;
Further stages.;
DOI:10.1039/b205408f
- Guidance literature:
-
Multi-step reaction with 7 steps
1.1: tert-butyllithium / tetrahydrofuran; pentane / 0.42 h / -78 - -42 °C
1.2: tetrahydrofuran; pentane / -78 - 20 °C
2.1: NaI / acetone / 48 h / Heating
3.1: n-butyllithium / tetrahydrofuran; hexane / 0 - 20 °C
3.2: HMPA / tetrahydrofuran; hexane / 48 h / 20 °C
4.1: 1.38 g / tetrabutylammonium fluoride / tetrahydrofuran / 0.5 h / 20 °C
5.1: CHCl3 / 2 h / Irradiation
6.1: m-chloroperbenzoic acid / CHCl3 / 0.33 h
7.1: 2.70 g / MgSO4 / benzene / 1 h / Heating
With
n-butyllithium; tetrabutyl ammonium fluoride; tert.-butyl lithium; magnesium sulfate; 3-chloro-benzenecarboperoxoic acid; sodium iodide;
In
tetrahydrofuran; hexane; chloroform; acetone; pentane; benzene;
DOI:10.1021/jo026595t
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: NaI / acetone / 48 h / Heating
2.1: n-butyllithium / tetrahydrofuran; hexane / 0 - 20 °C
2.2: HMPA / tetrahydrofuran; hexane / 48 h / 20 °C
3.1: 1.38 g / tetrabutylammonium fluoride / tetrahydrofuran / 0.5 h / 20 °C
4.1: CHCl3 / 2 h / Irradiation
5.1: m-chloroperbenzoic acid / CHCl3 / 0.33 h
6.1: 2.70 g / MgSO4 / benzene / 1 h / Heating
With
n-butyllithium; tetrabutyl ammonium fluoride; magnesium sulfate; 3-chloro-benzenecarboperoxoic acid; sodium iodide;
In
tetrahydrofuran; hexane; chloroform; acetone; benzene;
DOI:10.1021/jo026595t