*,R^*)>-2,2-Dimethyl-α-<5-<(phenylmethoxy)methyl>-2-furanyl>-1,3-dioxolane-4-methanol

Base Information

• Chemical Name: *,R^*)>-2,2-Dimethyl-α-<5-<(phenylmethoxy)methyl>-2-furanyl>-1,3-dioxolane-4-methanol
• CAS No.: 119947-93-2
• Molecular Formula: C₁₈H₂₂O₅
• Molecular Weight: 318.37

Synonyms:*,R^*)>-2,2-Dimethyl-α-<5-<(phenylmethoxy)methyl>-2-furanyl>-1,3-dioxolane-4-methanol

Chemical Property of *,R^*)>-2,2-Dimethyl-α-<5-<(phenylmethoxy)methyl>-2-furanyl>-1,3-dioxolane-4-methanol

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of *,R^*)>-2,2-Dimethyl-α-<5-<(phenylmethoxy)methyl>-2-furanyl>-1,3-dioxolane-4-methanol

There total 5 articles about *,R^*)>-2,2-Dimethyl-α-<5-<(phenylmethoxy)methyl>-2-furanyl>-1,3-dioxolane-4-methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[(R)-(5-Benzyloxymethyl-furan-2-yl)-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methoxy]-tert-butyl-dimethyl-silane → *,R*)>-2,2-Dimethyl-α-<5-<(phenylmethoxy)methyl>-2-furanyl>-1,3-dioxolane-4-methanol (119947-93-2)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 8h; Yield given; Ambient temperature;

DOI:10.1021/jo00023a028

Reference yield:

Benzyloxymethyl chloride (3587-60-8) → *,R*)>-2,2-Dimethyl-α-<5-<(phenylmethoxy)methyl>-2-furanyl>-1,3-dioxolane-4-methanol (119947-93-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) t-BuLi / 1.) THF, -78 to 0 deg C, 4 h, 2.) 0 to 25 deg C, 12 h

2: (n-Bu)4NF / tetrahydrofuran / 12 h / 25 °C

With tetrabutyl ammonium fluoride; tert.-butyl lithium; In tetrahydrofuran;

DOI:10.1021/ja00188a060

Reference yield:

*,R*)>-(2,2-Dimethyl-α-(2-furanyl)-1,3-dioxolan-4-yl)methyl tert-butyldimethylsilyl ether (119947-92-1) → *,R*)>-2,2-Dimethyl-α-<5-<(phenylmethoxy)methyl>-2-furanyl>-1,3-dioxolane-4-methanol (119947-93-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) t-BuLi / 1.) THF, -78 to 0 deg C, 4 h, 2.) 0 to 25 deg C, 12 h

2: (n-Bu)4NF / tetrahydrofuran / 12 h / 25 °C

With tetrabutyl ammonium fluoride; tert.-butyl lithium; In tetrahydrofuran;

DOI:10.1021/ja00188a060

upstream raw materials:

Benzyloxymethyl chloride

*,R^*)>-(2,2-Dimethyl-α-(2-furanyl)-1,3-dioxolan-4-yl)methyl tert-butyldimethylsilyl ether

2,2-dimethyl-4-(2-furyl)hydroxymethyl-1,3-dioxolane

2,3-isopropylidene-glyceraldehyde

Downstream raw materials:

(R)-6-Benzyloxymethyl-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-6-hydroxy-6H-pyran-3-one

Methyl 3-deoxy-7,8-O-(1-methylethylidene)-1-O-(phenylmethyl)-α-D-manno-2-octulopyranoside cyclic carbonate

Methyl 3,4-dideoxy-7,8-O-(1-methylethylidene)-1-O-(phenylmethyl)-α-D-arabino-oct-3-en-2-ulopyranoside carbamate

Methyl 3-deoxy-3-iodo-7,8-O-(1-methylethylidene)-1-O-(phenylmethyl)-D-glycero-α-D-galacto-2-octulopyranoside cyclic carbonate

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