IrCl(η-cyclo-octa-1,5-diene)(triphenylphosphine)

Base Information

• Chemical Name: IrCl(η-cyclo-octa-1,5-diene)(triphenylphosphine)
• CAS No.: 12115-50-3
• Molecular Formula: C₂₆H₂₇ClIrP
• Molecular Weight: 598.147
• Mol file: 12115-50-3.mol

Synonyms:IrCl(η-cyclo-octa-1,5-diene)(triphenylphosphine)

Chemical Property of IrCl(η-cyclo-octa-1,5-diene)(triphenylphosphine)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of IrCl(η-cyclo-octa-1,5-diene)(triphenylphosphine)

There total 6 articles about IrCl(η-cyclo-octa-1,5-diene)(triphenylphosphine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

bis(1,5-cyclooctadiene)diiridium(I) dichloride (12112-67-3) + triphenylphosphine (603-35-0) → {IrCl(cod)PPh3} (12115-50-3)

Guidance literature:

In dichloromethane; at 20 ℃; for 2h; Inert atmosphere; Schlenk technique;

DOI:10.1002/ejic.201402810

Reference yield: 49.0%

bis(1,5-cyclooctadiene)diiridium(I) dichloride (12112-67-3) + benzaldehyde (100-52-7) + triphenylphosphine (603-35-0) → {IrCl(cod)PPh3} (12115-50-3) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

In toluene; at 110 ℃; for 0.5h; Schlenk technique; Inert atmosphere;

DOI:10.1021/ja5106943

Reference yield:

chloro(1,5-cyclooctadiene)iridium(I) dimer → IrCl(η-cyclo-octa-1,5-diene)(triphenylphosphine) (12115-50-3)

Guidance literature:

With triphenylphosphine; In not given;

DOI:10.1039/DT9780000340

upstream raw materials:

Ir(η-cyclo-octa-1,5-diene)(triphenylphosphine)2(1+)

[1,2:5,6-η-(1,5-cycloodiene)]triphenylphosphinechlororuthenium

triphenylphosphine

bis(1,5-cyclooctadiene)diiridium(I) dichloride

Downstream raw materials:

[1,2:5,6-η-(1,5-cycloodiene)]triphenylphosphinechlororuthenium

η4-1,5-cyclooctadiene-μ-2,4-pentanedionato-iridium(I)

trans-carbonyl(chloro)bis(triphenylphosphine)rhodium(I)

bis(triphenylphosphine)carbonyliridium(I) chloride

Refernces

• 1、 Tejel, Cristina,Del Rio, M. Pilar,Asensio, Laura,Van Den Bruele, Fieke J.,Ciriano, Miguel A.,Tsichlis I Spithas, Nearchos,Hetterscheid, Dennis G. H.,De Bruin, Bas. "Cooperative double deprotonation of bis(2-picolyl)amine leading to unexpected bimetallic mixed valence (M-I, MI) rhodium and iridium complexes". . p. 7524 - 7534. Retrieved 2011.
• 2、 Olsen, Esben P. K.,Singh, Thishana,Harris, Pernille,Andersson, Pher G.,Madsen, Robert. "Experimental and theoretical mechanistic investigation of the iridium-catalyzed dehydrogenative decarbonylation of primary alcohols". . p. 834 - 842. Retrieved 2015/01/30.