(1R,3R,4R,5S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-4-trimethylsilanyloxy-2,6-dioxa-bicyclo[3.1.0]hexane

Base Information

Chemical Name:(1R,3R,4R,5S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-4-trimethylsilanyloxy-2,6-dioxa-bicyclo[3.1.0]hexane
CAS No.:127761-84-6
Molecular Formula:C₂₄H₃₄O₄Si₂
Molecular Weight:442.703
Hs Code.:

Synonyms:(1R,3R,4R,5S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-4-trimethylsilanyloxy-2,6-dioxa-bicyclo[3.1.0]hexane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R,3R,4R,5S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-4-trimethylsilanyloxy-2,6-dioxa-bicyclo[3.1.0]hexane

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Technology Process of (1R,3R,4R,5S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-4-trimethylsilanyloxy-2,6-dioxa-bicyclo[3.1.0]hexane

There total 1 articles about (1R,3R,4R,5S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-4-trimethylsilanyloxy-2,6-dioxa-bicyclo[3.1.0]hexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 127791-68-8
1,4-anhydro-5-O-(tert-butyldiphenylsilyl)-2-deoxy-3-O-(trimethylsilyl)-D-erythro-pent-1-enitol

: 127761-84-6
(1R,3R,4R,5S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-4-trimethylsilanyloxy-2,6-dioxa-bicyclo[3.1.0]hexane

Guidance literature:: With 3,3-dimethyldioxirane; In dichloromethane; acetone; at 0 ℃; for 0.5h;
DOI:10.1021/jo00300a049

Reference yield: 52.0%

: 127761-84-6
(1R,3R,4R,5S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-4-trimethylsilanyloxy-2,6-dioxa-bicyclo[3.1.0]hexane

: 7288-28-0
2,4-bis(trimethylsiloxy)-5-methylpyrimidine

: 127761-86-8
1-(3'-(trimethylsilyl)-5'-(tert-butyldiphenylsilyl)-α-D-arabinofuranosyl)-5-methyl-2,4(1H,3H)-pyrimidinedione

: 1-[(2S,3S,4R,5R)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-3,4-bis-trimethylsilanyloxy-tetrahydro-furan-2-yl]-5-methyl-1H-pyrimidine-2,4-dione

Guidance literature:: In acetonitrile; for 18h; Ambient temperature;
DOI:10.1021/jo00300a049

Reference yield:

: 127761-84-6
(1R,3R,4R,5S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-4-trimethylsilanyloxy-2,6-dioxa-bicyclo[3.1.0]hexane

: 127761-89-1,4645-02-7
1-(2,3,5-tri-O-acetyl-α-D-arabinofuranosyl)thymine

Guidance literature:: Multi-step reaction with 2 steps

1: 2) 2percent HF / 1) acetonitrile, 18h, room temp., 2) acetonitrile, 10.5h, room temp.

2: 94 percent / DMAP

With dmap; hydrogen fluoride;
DOI:10.1021/jo00300a049