5-(2'.6'.6'.-trimethyl-1'-cyclohexenyl)-1-benzenesulphonyl-3-methyl 2.4-pentadiene

Base Information

Chemical Name:5-(2'.6'.6'.-trimethyl-1'-cyclohexenyl)-1-benzenesulphonyl-3-methyl 2.4-pentadiene
CAS No.:59057-12-4
Molecular Formula:C₂₁H₂₈O₂S
Molecular Weight:344.518
Hs Code.:

Synonyms:5-(2'.6'.6'.-trimethyl-1'-cyclohexenyl)-1-benzenesulphonyl-3-methyl 2.4-pentadiene

Suppliers and Price of 5-(2'.6'.6'.-trimethyl-1'-cyclohexenyl)-1-benzenesulphonyl-3-methyl 2.4-pentadiene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 5-(2'.6'.6'.-trimethyl-1'-cyclohexenyl)-1-benzenesulphonyl-3-methyl 2.4-pentadiene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 5-(2'.6'.6'.-trimethyl-1'-cyclohexenyl)-1-benzenesulphonyl-3-methyl 2.4-pentadiene

There total 7 articles about 5-(2'.6'.6'.-trimethyl-1'-cyclohexenyl)-1-benzenesulphonyl-3-methyl 2.4-pentadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 3-methyl-1-(phenylsulfanyl)-5-(2,6,6-trimethylcyclohex-1-enyl)penta-2,4-diene

: 38987-91-6
5-(2,6,6-trimethyl-cyclohex-1-enyl)-3-methyl-1-phenyl-sulphonyl-penta-2,4-diene

: 59057-12-4
5-(2'.6'.6'.-trimethyl-1'-cyclohexenyl)-1-benzenesulphonyl-3-methyl 2.4-pentadiene

Guidance literature:: With LiNbMoO₆; dihydrogen peroxide; In methanol; water; benzene; at 20 ℃; for 6h;
DOI:10.1002/hlca.200390211

Reference yield:

: 134436-09-2,134461-82-8
[(2E,4E)-1-Benzenesulfonyl-3-methyl-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-2,4-dienyl]-trimethyl-silane

: 38987-91-6,50464-14-7,59057-12-4
[(2E,4E)-3-Methyl-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-2,4-diene-1-sulfonyl]-benzene

Guidance literature:: With sodium methylate; In methanol;
DOI:10.1016/S0040-4039(00)92030-6

Reference yield:

: 56691-74-8
{[(2,6,6-trimethyl-1-cyclohexen-1-yl)methyl]sulfonyl}benzene

: 59057-12-4
5-(2'.6'.6'.-trimethyl-1'-cyclohexenyl)-1-benzenesulphonyl-3-methyl 2.4-pentadiene

Guidance literature:: Multi-step reaction with 3 steps

1: 93 percent / BuLi / tetrahydrofuran; hexane / -78 - 20 °C

2: 80 percent / NaOEt / ethanol / 10 h / Heating

3: 23 percent / LiNbMoO₆; H₂O₂ / methanol; benzene; H₂O / 6 h / 20 °C

With n-butyllithium; LiNbMoO₆; dihydrogen peroxide; sodium ethanolate; In tetrahydrofuran; methanol; ethanol; hexane; water; benzene;
DOI:10.1002/hlca.200390211