38987-91-6

Basic information

• Product Name: Benzene, [[(2E,4E)-3-methyl-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,4-pentadienyl] sulfonyl]-
• CAS NO: 38987-91-6
• Molecular Formula: C21H28O2S
• Molecular Weight: 344.518
• Mol File: 38987-91-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, [[(2E,4E)-3-methyl-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,4-pentadienyl] sulfonyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [[(2E,4E)-3-methyl-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,4-pentadienyl] sulfonyl]-(38987-91-6)
• EPA Substance Registry System: Benzene, [[(2E,4E)-3-methyl-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,4-pentadienyl] sulfonyl]-(38987-91-6)

Safety Data

• Hazardous Substances Data: 38987-91-6(Hazardous Substances Data)

Upstream product

• 59057-30-6 (1E)-1-(2,6,6-trimethylcyclohex-1-enyl)-3-methyl-1,4-pentadien-3-ol 
• 134436-09-2 [(2E,4E)-1-Benzenesulfonyl-3-methyl-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-2,4-dienyl]-trimethyl-silane 
• 79-77-6 (E)-β-ionone 
• 56691-74-8 {[(2,6,6-trimethyl-1-cyclohexen-1-yl)methyl]sulfonyl}benzene 
• 873-55-2 sodium benzenesulfonate 
• 38987-92-7 3-methyl-5-bromo-1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3-pentadiene 

Downstream Products

• 52449-25-9 (6E,8E)-5-Benzenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-1,6,8-trien-3-ol 
• 50465-60-6 9-(2,6,6-Trimethyl-cyclohex-1-enyl)-5-phenyl-sulphonyl-3,7-dimethyl-1-acetoxy-nona-2,6,8-triene 
• 41551-56-8 methyl 5-benzenesulphonyl-3.7-dimethyl-9-(2'.6'.6'.trimethyl-cyclohexen-1'-yl)-2.6.8-nonatrienoate 
• 251291-84-6 bis(11-benzenesulfonyl-11,12-dihydroretinyl) sulfide 
• 50465-62-8 9-(2,6,6-Trimethyl-cyclohex-1-enyl)-5-phenyl-sulphonyl-3,7-dimethyl-1-methoxy-nona-2,6,8-triene 
• 791102-85-7 C₃₂H₄₀O₂S₂ 
• 791102-84-6 C₃₂H₄₀O₃S 
• 791102-86-8 2-[(2E,6E,8E)-5-Benzenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6,8-trienyl]-isoindole-1,3-dione 
• 791102-83-5 [(1E,3E,7E)-9-((E)-3,7-Dimethyl-octa-2,6-dienyloxy)-3,7-dimethyl-1-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-1,3,7-triene-5-sulfonyl]-benzene 
• 791102-88-0 (S)-3-{4-[(2E,6E,8E)-5-Benzenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6,8-trienyloxy]-phenyl}-2-tert-butoxycarbonylamino-propionic acid methyl ester 
• 791102-87-9 (8R,9S,13S,14S)-3-[(2E,6E,8E)-5-Benzenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6,8-trienyloxy]-13-methyl-6,7,8,9,11,12,13,14,15,16-decahydro-cyclopenta[a]phenanthren-17-one 
• 302-79-4 all-trans-retinoic-acid 
• 842127-19-9 (2E,6E,8E)-5-Benzenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6,8-trienoic acid (8R,9S,13S,14S,17S)-17-acetoxy-13-methyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-3-yl ester 
• 842127-17-7 5-benzenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6,8-trienoic acid 17-(1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester 

Relevant articles and documents

Allylic sulfones containing triene moieties as key synthons for carotenoid synthesis

An efficient synthetic method for the allylic sulfone 2 containing a conjugated triene moiety has been proposed involving i) coupling of allylic sulfones 4 with the C5 bromoallylic sulfide 5, ii) base-promoted dehydrosulfonation in the presence of allylic sulfide, and iii) selective oxidation of the resulting trienyl sulfide to the corresponding sulfone. Total synthesis of lycopene starting from the C15 allylic sulfone 2b has been described, where the new C10 bis(chloroallylic) sulfone 11 proved to be a useful substitute for the C10 bis(chloroallylic) sulfide 3, which did not require the problematic chemoselective sulfur oxidation in a conjugated polyene.

Organic syntheses with sulfones XXXIII. A laboratory procedure for the synthesis of retinoic acid

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Synthesis of vitamin A via sulfones: A C15 sulfone route

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