2-(METHYLSULFINYL)BENZENOL

Base Information

• Chemical Name: 2-(METHYLSULFINYL)BENZENOL
• CAS No.: 1074-02-8
• Molecular Formula: C7H8O2S
• Molecular Weight: 156.205
• Hs Code.: 2930909090
• Mol file: 1074-02-8.mol

Synonyms:Phenol,o-(methylsulfinyl)- (7CI,8CI);2-(Methylsulfinyl)phenol;

Chemical Property of 2-(METHYLSULFINYL)BENZENOL

Chemical Property:

• Vapor Pressure: 0.000103mmHg at 25°C
• Melting Point: 118-122 °C
• Refractive Index: 1.653
• Boiling Point: 327.9 °C at 760 mmHg
• Flash Point: 152.1 °C
• PSA: 56.51000
• Density: 1.36 g/cm³
• LogP: 1.99530
• Storage Temp.: Keep Cold

Purity/Quality:

97% ^*data from raw suppliers

2-(Methylsulfinyl)phenol ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 41
• Safety Statements: 26-39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-(METHYLSULFINYL)BENZENOL

There total 5 articles about 2-(METHYLSULFINYL)BENZENOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

2-(methylsulfenyl)phenol (1073-29-6) → 2-(Methylsulfinyl)phenol (1074-02-8)

Guidance literature:

With 3,3-dimethyldioxirane; In acetone; at 0 ℃;

DOI:10.1039/b313714g

Reference yield: 95.0%

[Ru(2,2′-bipyridine)2(2-(methylsulfinyl)phenolato)](PF6) → 2-(Methylsulfinyl)phenol (1074-02-8)

Guidance literature:

With trifluoroacetic acid; In acetonitrile; at 80 ℃; for 2h; Inert atmosphere;

DOI:10.1021/ic502898e

Reference yield: 30.0%

(2-methylsulfanylphenyl)boronic acid (168618-42-6) → 2-(methylsulfenyl)phenol (1073-29-6) + 2-(Methylsulfinyl)phenol (1074-02-8)

Guidance literature:

With [(hydrotris(3,5-diphenyl-pyrazol-1-yl)borate)Fe^II(benzilate)]; oxygen; In benzene; at 20 ℃; for 0.333333h;

DOI:10.1021/acs.inorgchem.5b01198

upstream raw materials:

2-(methylsulfenyl)phenol

phenol

ortho-mercaptophenol

(2-methylsulfanylphenyl)boronic acid

Downstream raw materials:

2-(methylsulfenyl)phenol

cis-[Pt(PPh₃)2(2-(methylsulfinyl)phenolate)2]