2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl azide

Base Information

• Chemical Name: 2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl azide
• CAS No.: 158964-83-1
• Molecular Formula: C₃₄H₃₅N₃O₅
• Molecular Weight: 565.669
• Mol file: 158964-83-1.mol

Synonyms:2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl azide

Chemical Property of 2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl azide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl azide

There total 10 articles about 2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

2,3,4,6-tetra-O-benzyl-D-mannopyranose (4132-28-9,4291-69-4,6386-24-9,6564-72-3,59531-24-7,69257-52-9,78184-89-1,78609-16-2,78609-17-3,78609-18-4,96553-53-6,104111-61-7,131347-08-5) + bis(p-nitrophenyl) azidophosphonate (51250-91-0) + 1,8-diazabicyclo[5.4.0]undec-7-ene (6674-22-2,83329-50-4) → 2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl azide (158964-83-1)

Guidance literature:

In N,N-dimethyl-formamide;

Reference yield: 75.0%

2,3,4,6-tetra-O-benzyl-D-mannopyranose (4132-28-9,4291-69-4,6386-24-9,6564-72-3,59531-24-7,69257-52-9,78184-89-1,78609-16-2,78609-17-3,78609-18-4,96553-53-6,104111-61-7,131347-08-5) → 2,3,4,6-tetra-O-benzyl-β-D-mannopyranosyl azide (150370-49-3) + 2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl azide (158964-83-1)

Guidance literature:

With bis(p-nitrophenyl) azidophosphonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; In N,N-dimethyl-formamide; for 2h; Ambient temperature;

DOI:10.1039/a705768g

Reference yield: 69.0%

C43H41NO7 → 2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl azide (158964-83-1)

Guidance literature:

With gold(III) chloride; trimethylsilylazide; 3F₆Sb^(1-)*3Ag⁽¹⁺⁾; In dichloromethane; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1039/c5ob00248f

upstream raw materials:

2,3,4,6-tetra-O-benzyl-D-mannopyranose

2,3,4,6-tetra-O-benzyl-1-O-acetyl-α-D-mannopyranose

bis(p-nitrophenyl) azidophosphonate

1,8-diazabicyclo[5.4.0]undec-7-ene

Downstream raw materials:

1-amino-2,3,4,6-tetra-O-benzyl-1-deoxy-β-D-mannopyranose

6-(2,3,4,6-tetra-O-benzyl-β-D-mannopyranosylamino)-9-(2-(trimethylsilyl)-ethoxymethyl)-purine

(3R)-1-[1-(methoxycarbonyl)isopropyl]-3-(2-nitrobenzenesulfonamino)-3-[1-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-1,2,3-triazol-4-ylmethyl]-azetidin-2-one

1-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-4-hydroxymethyl-1H-1,2,3-triazole