[(C₅Me₅)Al(9-phenyl-9-borafluorene)]

Base Information

• Chemical Name: [(C₅Me₅)Al(9-phenyl-9-borafluorene)]
• CAS No.: 514791-45-8
• Molecular Formula: C₂₈H₂₈AlB
• Molecular Weight: 402.323
• Mol file: 514791-45-8.mol

Synonyms:[(C₅Me₅)Al(9-phenyl-9-borafluorene)]

Chemical Property of [(C₅Me₅)Al(9-phenyl-9-borafluorene)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(C₅Me₅)Al(9-phenyl-9-borafluorene)]

There total 4 articles about [(C₅Me₅)Al(9-phenyl-9-borafluorene)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

tetrkis(pentametylcyclopentadienyl)tetraalane(I) + 5-phenyl-5H-dibenzo[d,b]borole (14010-93-6) → [(C5Me5)Al(9-phenyl-9-borafluorene)] (514791-45-8)

Guidance literature:

In toluene; byproducts: Al; (Ar); using Schlenk techniques; mixing of ((C5Me5)Al)4 and 9-phenyl-9-borafluorene in glass bomb in glovebox, addn. of toluene at room temp., heating at 60-70°C for 1 h in an oil bath; filtration, layering with pentane, cooling at -35°C overnight, crystn., washing with cold pentane and drying under vac., elem. anal.;

DOI:10.1021/om0209935

Reference yield:

2,2'-dibromobiphenyl (13029-09-9) → [(C5Me5)Al(9-phenyl-9-borafluorene)] (514791-45-8)

Guidance literature:

Multi-step reaction with 3 steps

1: n-C₄H₉Li / diethyl ether

2: toluene

3: toluene

With n-C₄H₉Li; In diethyl ether; toluene;

DOI:10.1021/om0209935

Reference yield:

phenylborondichloride (873-51-8) → [(C5Me5)Al(9-phenyl-9-borafluorene)] (514791-45-8)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene

2: toluene

In toluene;

DOI:10.1021/om0209935

upstream raw materials:

5-phenyl-5H-dibenzo[d,b]borole

phenylborondichloride

5,5-dimethyl-5H-dibenzo[b,d]stannole

2,2'-dibromobiphenyl

Downstream raw materials:

aluminium