trans-mer-Re(H)(PPh₃)2(CO)3

Base Information

Chemical Name:trans-mer-Re(H)(PPh₃)2(CO)3
CAS No.:25734-54-7
Molecular Formula:C₃₉H₃₁O₃P₂Re
Molecular Weight:795.828
Hs Code.:

Synonyms:trans-mer-Re(H)(PPh₃)2(CO)3

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Chemical Property of trans-mer-Re(H)(PPh₃)2(CO)3

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Technology Process of trans-mer-Re(H)(PPh₃)2(CO)3

There total 19 articles about trans-mer-Re(H)(PPh₃)2(CO)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 81368-84-5
(C₅H₆)Re(P(C₆H₅)3)2H₃

: 25734-54-7
[Re(P(C₆H₅)3)2(CO)3(H)]

Guidance literature:: With CO; In toluene; High Pressure; a soln. of a cyclopepentadiene complex was placed in a bomb reactor under 350 psi of CO, after 8 h at 40°C the reactor was opened and the solvent was removed; elem. anal.;

Reference yield: 77.0%

: 16457-30-0
hydridopentacarbonylrhenium(I)

: 603-35-0
triphenylphosphine

: 25734-54-7
trans-mer-Re(H)(PPh₃)2(CO)3

Guidance literature:: In toluene; byproducts: CO; air and moisture exclusion; -78°C, evacuation, warming (room temp.), heating (100-130°C, 40-140 h), evacuation (every 12 h); solvent removal (vac.);
DOI:10.1021/ja9643228

Reference yield: 64.0%

: 16853-85-3
lithium aluminium tetrahydride

: 19394-85-5
trans,mer-[Re(CO)3Cl(PPh₃)2]

: 25734-54-7
trans-mer-Re(H)(PPh₃)2(CO)3

Guidance literature:: In tetrahydrofuran; LiAlH4 is added to a suspn. of ReCl(CO)3(PPh3)2 in THF; the mixt. stirred at room temp for 15 min; the resulting suspn. cooled to 0°C and hydrolysed by dropwise addn. of H2O in THF; the mixt. dried with anhyd. Na2SO4 for 15 min and filtered; the filtrate evapd. in vac.; addn. of hexane resulted in the pptn. of a solid, which is filtered off, washed with hexane and dried in vac.; elem. anal.;