Rhenium,pentacarbonylhydro-, (OC-6-21)-

Base Information

• Chemical Name: Rhenium,pentacarbonylhydro-, (OC-6-21)-
• CAS No.: 16457-30-0
• Molecular Formula: C5H O5 Re
• Molecular Weight: 327.267

Synonyms:Hydrogenpentacarbonylrhenate(-I) (7CI); Rhenium, pentacarbonylhydro- (8CI); Pentacarbonylhydridorhenium;Pentacarbonylhydrorhenium; Pentacarbonylrheniumhydride

Chemical Property of Rhenium,pentacarbonylhydro-, (OC-6-21)-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
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MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Rhenium,pentacarbonylhydro-, (OC-6-21)-

There total 17 articles about Rhenium,pentacarbonylhydro-, (OC-6-21)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(CO)5ReCHC6H5OSi(CH3)3 → hydridopentacarbonylrhenium(I) (16457-30-0) + (CO)5ReCHOHC6H5 + benzaldehyde (100-52-7)

Guidance literature:

With HF; In tetrahydrofuran-d8; HF gas, -78 to -50°C; not sepd., detected by NMR;

DOI:10.1021/ja00267a015

Reference yield: 67.0%

(CO)5ReCHC6H5OSi(CH3)3 + tetra-n-butylammoniumfluoride trihydrate (22206-57-1,153005-55-1) → hydridopentacarbonylrhenium(I) (16457-30-0) + (CO)5ReCHOHC6H5 + benzaldehyde (100-52-7)

Guidance literature:

In dichloromethane-d2; CD2Cl2, Bu4NF*3H2O, 25°C, 5 min; not sepd., detected by NMR;

DOI:10.1021/ja00267a015

Reference yield:

(CO)5ReCOCOC6H5 → hydridopentacarbonylrhenium(I) (16457-30-0) + (CO)5ReCHOHC6H5 + benzaldehyde (100-52-7)

Guidance literature:

Multi-step reaction with 3 steps

1: Li(C₂H₅)3BH / tetrahydrofuran

2: H₂O / acetone

3: [⁽²⁾H₆]acetone

With Li(C₂H₅)3BH; H₂O; In tetrahydrofuran; [⁽²⁾H₆]acetone; acetone;

DOI:10.1021/ja00267a015

upstream raw materials:

{Et₄N}{HFe(CO)3PPh₃}

(Re(CO)6)⁽¹⁺⁾*BF₄^(1-)=(Re(CO)6)(BF₄)

{H₃BRe(CO)5}^(1-)

[Re3(μ-H)3(CO)12]

Downstream raw materials:

rhenium(I) pentacarbonyl chloride

dichloroborane

[Re(P(C₆H₅)3)(CO)4(H)]

rheniumpentacarbonyl

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